Acids, Alkalis and Salts

by George Henry Joseph Adlam

The first and possibly the most serious difficulty encountered in the working of the contact process was the frequent interruption caused by the loss of activity of the contact substance. Iron pyrites always contains arsenic which volatilizes on heating, and this quickly caused the platinum to lose its activity, or, as it was sometimes rather fancifully expressed, “poisoned the catalyst.” Dust also is inevitable, and this, carried forward mechanically with the stream of gas, settled on the contact substance and caused the action to cease.

To get over this difficulty it is necessary to purify the gases. They are first passed slowly through channels in which the coarser particles of dust settle down. Steam is injected into the mixture to wash out the finer particles of solid, and also to get rid of arsenic, and then the gases are passed through scrubbers. Before being admitted to the contact furnace, the moist gas is submitted to an optical test. It is passed through a tube, the ends of which are transparent; a bright light is placed at one end and viewed from the other through a column of gas of considerable length. If the purification process is working satisfactorily, there is a complete absence of fog. The gases are then dried by passing through concentrated sulphuric acid and admitted to the contact tubes.

In all operations carried out on a large scale, the regulation of temperature is a matter of some difficulty. In the case which we are considering, the most suitable temperature range is a rather narrow one, and the difficulty of keeping within the limits is very much increased by the large amount of heat given out when the sulphur dioxide and oxygen combine. The result of the failure to maintain the temperature at a fairly constant level was that the process worked in a very irregular manner, for as soon as it was working really well and sulphur trioxide was being formed rapidly, the heat given out by the reaction itself was also great, and consequently, the higher temperature limit was exceeded.

The method of controlling the temperature in the contact process is worth noting, because it is really ingenious. The tubes containing the platinized asbestos are surrounded by wider concentric tubes. The gases which are about to enter the contact furnace pass through the annular space between the two tubes, and are thereby heated to the required temperature, while at the same time they serve to cool the inner tubes. The most satisfactory temperature is about 400° C. The tubes are first warmed to 300° C. to start the reaction, and thereafter the heat evolved by the reaction itself is sufficient to keep it going.

The absorption of the sulphur trioxide also caused some difficulty at first. This substance reacts most violently with water, dissolving with a hissing sound like that produced when a red-hot poker is plunged into water. At the same time great heat is developed, and consequently, much of the sulphur trioxide is vaporized, and in that way lost. This difficulty was got over by using 98 per cent. sulphuric acid for the absorption, the acid being kept at this strength by the simultaneous addition of water.

The contact process has some very distinct advantages over the older lead chamber process. The plant covers a much smaller area than the bulky lead chambers. Although the preliminary purification of the gases is somewhat tedious and costly, this is in great measure compensated by the purity of the acid produced. No separate plant is required for concentration and purification, as in the older process. Finally, sulphuric acid of any concentration can be produced at will, including the fuming acid, which is required as a solvent for indigo, and in the manufacture of artificial indigo and other organic chemicals.

The lead chamber process produces what is called chamber sulphuric acid very cheaply. Although this is only a 60-70 per cent. solution and very impure, nevertheless, it is quite good enough for the heavy chemical trade, particularly for the first stage of the Leblanc soda process, and for making superphosphate. These two industries alone consume many thousands of tons of this sulphuric acid every year. Probably for some years to come the two processes will continue to exist side by side, but it may be doubted whether new works will now be installed to make sulphuric acid by the lead chamber process.

Properties of Sulphuric Acid. The pure non-fuming acid is a colourless oily liquid whose density is 1·84. It mixes with water in all proportions, yielding dilute sulphuric acid, and it also dissolves sulphur trioxide, yielding the fuming acid.

The mixing of sulphuric acid and water is accompanied by an evolution of heat and by contraction in volume. It is an operation which must be carried out with great care, the acid being always poured into the water, otherwise the water floats on the heavier acid, and so much heat is developed at the surface of separation that some of the water will be suddenly converted into steam, and this, escaping from the liquid with explosive violence, may cause the contents of the vessel to be scattered about.

Strong sulphuric acid chars most organic substances. From substances such as wood, sugar, paper, starch, it withdraws the elements of water, liberating carbon. Since it acts in the same way upon human flesh, it is clear that the concentrated acid must be handled with very great care, for it causes most painful burns. For this reason, vitriol throwing has always been regarded as a most serious and dastardly offence. A simple first-aid remedy for burns produced by sulphuric acid is the liberal application of an emulsion of linseed oil and lime water. The lime, being an alkali, neutralizes the acid, and the oil excludes air from the wound.