Recovery of the Nitrogen Peroxide. If the gases from the last chamber passed directly into the chimney shaft, there would be a total loss of the oxides of nitrogen, and the consequence of this would be that more than 2 cwt. of nitre would have to be used for the production of 1 ton of sulphuric acid. This would be a serious item in the cost of production, and it is therefore essential that this loss should be prevented.
The recovery of the oxides of nitrogen is effected in the Gay Lussac tower, a structure about 50 ft. in height, built of sheet lead and lined with acid-resisting brick. It is filled with flints, over which a slow stream of cold concentrated sulphuric acid is delivered from a tank at the top. As the gas from the last chamber passes up this tower, it meets the stream of acid coming down. This dissolves and retains the nitrogen peroxide. The acid which collects at the bottom of the tower is known as nitrated vitriol.
The next step is to bring the recovered nitrogen peroxide again into circulation. The nitrated vitriol is raised by compressed air to the top of the Glover tower, and as it trickles down over the flints in this tower it is diluted with water, while at the same time it meets the hot gases coming from the pyrites burners. Under these conditions, the nitrogen peroxide is liberated and carried along by the current of gas into the first lead chamber. The stream of cold acid coming down the Glover tower also serves to cool the hot gases before they enter the first chamber.
In order to complete the description of the works, it is necessary to add a note on the lead chambers themselves. The sheet lead used in their construction is of a very substantial character; it weighs about 7 lb. per square foot. The separate strips are joined together by autogenous soldering, that is, by fusing the edges together. In this way the presence of another metal is avoided; otherwise this would form a voltaic couple with the lead, and rapid corrosion would take place.
The size of the chambers has varied a great deal. In the early years of the nineteenth century, the capacity of a single chamber was probably not more than 1,000 cu. ft.; at the present time, 38,000 cu. ft. is an average size, and there may be three or five of these chambers. The necessity for this large amount of cubic space is easily accounted for. The reaction materials are all gases, and a gas occupies more than one thousand times as much space as an equal weight of a solid or liquid. Moreover, oxygen constitutes only about one-fifth of the total volume of air used in burning the pyrites; the other four-fifths is mainly nitrogen, which, though it does not enter into the reaction at all, has to pass through the chambers.
Modern Improvements. Among the modern innovations in the lead chamber process, the following are worthy of note. “Atomized water,” that is, water under high pressure delivered from a fine jet against a metal plate, has certain advantages over steam. In order to bring about a more rapid mixing of the gases in the chamber, it is proposed to make these circular instead of rectangular, and to deliver the gases tangentially to the sides. Another suggestion is to replace the lead chambers by towers containing perforated stoneware plates set horizontally. By this arrangement, since the holes are not placed opposite one another, the gases passing up the tower must take a zig-zag course. This makes for more efficient mixing.
THE CONTACT PROCESS
Sulphur Trioxide. When elements are combined in different proportions by weight, they produce different compounds. Thus, in the case of sulphur and oxygen, there are two well-known compounds, namely, sulphur dioxide and sulphur trioxide. In the former, a given weight of oxygen is combined with an equal weight of sulphur; in the latter, this same weight of sulphur is combined with 50 per cent. more oxygen. On this account, sulphur trioxide is spoken of as the higher oxide.
We can now state in general terms another method by which sulphuric acid can be built up from its elements. Sulphur, as we have seen, burns in oxygen, forming sulphur dioxide. This substance can then be made to unite with more oxygen to give sulphur trioxide, which, with water, yields sulphuric acid. There are three steps in this synthesis. The first, namely, sulphur to sulphur dioxide, has already been considered; the last, sulphur trioxide to sulphuric acid, only requires that sulphur trioxide and water shall be brought together: we can, therefore, confine our attention to the intermediate step, namely, the conversion of sulphur dioxide into trioxide.
This operation, when carried out in a chemical laboratory, is a very simple one. [Fig. 4] shows the necessary apparatus. Sulphur dioxide from a siphon of the liquefied gas and air from a gasholder are passed into the Woulff’s bottle A, containing concentrated sulphuric acid; this removes moisture from the gases. The drying process is completed in the tower B, which contains pumice stone soaked in sulphuric acid. The mixed gases then pass through the tube C, containing platinized asbestos heated to about 400° C.: the sulphur trioxide collects in the cooled receiver D.