Special Treatment of the Selenium.
“The first point to which we devoted our attention was reducing the resistance of crystalline selenium within manageable limits. The resistance of selenium cells, employed by former experimenters, was counted in millions of ohms; there is no record of a cell measuring less than 250,000 ohms in the dark. We have succeeded in producing cells measuring only 300 ohms in the dark and 150 in the light. Our predecessors all seemed to have used platinum for the conducting part of their cells, excepting Werner Siemens, who found that iron and copper would do. We have discovered that brass, although chemically acted upon by selenium, forms an excellent material; indeed, we are inclined to believe that the chemical action between brass and selenium has contributed to the lowness in resistance of our cells, an intimate union taking place between the two substances. In brass we have constructed many cells of diverse forms. One of them (two are described by Professor Bell), is cylindrical so that it may be used with a concave reflector instead of with a lens. It is composed of many metallic disks separated by mica disks slightly smaller in diameter. The spaces between the brass disks over the mica are filled with selenium, and the alternate brass disks are metallically connected. The selenium is applied to the cell duly heated: next comes annealing. To effect this an oven is inserted in a pot of linseed oil standing upon glass supports in another similar pot of linseed oil. The whole is then heated to about 214° C., and kept there for twenty-four hours, then allowed to cool down during forty to sixty hours until the temperature of ordinary air is reached.
A Perfected Transmitter.
“We have devised more than fifty forms of photophonic transmitters. In one of them (several others are described by Professor Bell), a beam of light passes through a lens of variable focus formed of two sheets of thin glass or mica containing between them a transparent liquid or gas. When vocal vibrations are communicated to this gas or liquid, they cause a vibratory change in the convexity of the glass surfaces with a corresponding change in the intensity of the light as it falls upon the selenium. We have found the simplest apparatus to consist in a plane mirror of flexible material, such as silvered mica or microscope glass, against the back of which the speaker’s voice is directed.
Selenium cylinder with reflector.
“A large number of trials of this apparatus have been made with the transmitting and receiving instruments so far apart that sounds could not be heard directly through the air. In a recent experiment Mr. Tainter operated the transmitting instrument, placed on the top of the Franklin School House in Washington, D. C.; the receiver being arranged in a window of my laboratory, at a distance of 213 metres. Upon placing the telephone to my ear, I heard distinctly from the illuminated receiver: ‘Mr. Bell, if you hear what I say, come to the window and wave your hat.’
“We have found that articulate speech can be reproduced by the oxyhydrogen light, and even by a beam from a kerosene lamp. The loudest effects follow upon interrupting the light by means of a perforated disk swiftly rotated. Because this apparatus is noiseless it allows a close approach of the receiver while not interfering with its message.
“We have endeavored to ascertain the nature of the rays which affect selenium, placing in the path of an intermittent beam various absorbing substances. In these experiments Professor Cross has rendered us aid. When a solution of alum, or bisulphide of carbon, is employed, there is but slight reduction in loudness, but a solution of iodine in bisulphide of carbon cuts off most of the audible effect. Even an opaque sheet of hard rubber is less obstructive.