A century ago the mastery of electricity began to unfold a new knowledge of properties, so wide and intimate as to recall the immense expansion of such knowledge that long before had followed upon the kindling of fire. The successors of Volta, as they reproduced his crown of cups, asked, What metals dissolved in what liquids will give us an electric current at least outlay? Then followed the further question, What metals drawn into wire will bear currents afar with least loss? With the invention of the electro-magnet came another query, What kinds of iron are most swiftly and largely magnetized by a current; and when the current ceases, which of them loses its magnetism in the shortest time? Plainly enough the electrician regards copper, zinc, iron, steel, acids, alkalis from a new point of view; he discovers in them properties which until his advent had been utterly ignored.
Among the properties of matter revealed by electricity none are more striking than those displayed in tubes containing highly rarified gases. The study of their phenomena has led to discoveries which bring us within view of an ultimate explanation of properties, an understanding of how matter is atomically built. All this began simply enough as Plucker, in 1859, sent an electric discharge through a tube fairly well exhausted, producing singular bands of color. Geissler, afterward using tubes more exhausted, produced bands of still higher variegation. In 1875 Professor William Crookes devised the all but vacuous tube which bears his name, through which he sent electric pulses from a cathode pole, revealing what he called “radiant matter,” as borne in a beam of cathode rays, as much more tenuous than ordinary gases as these are more rare than liquids. In 1894 Professor Philipp Lenard observed that cathode rays passed through a thin plate of aluminium, much as daylight takes its way through a film of translucent marble. Next year came the epoch-making discovery of Professor Conrad Wilhelm Röntgen that cathode rays consist in part of X-rays which readily pass through human flesh, so as to cast shadows of bones upon a photographic plate. Cathode rays make air a fairly good conductor of electricity, while ordinary air is non-conducting in an extreme degree. This singular power is also possessed by the ultra-violet rays of sunshine, as readily shown by an electroscope. In 1897 Professor Joseph J. Thomson, of Cambridge University, demonstrated that cathode rays are made up of corpuscles, or electrons, about one-thousandth part the size of a hydrogen atom, and bearing a charge of negative electricity. Such electrons form a small part of every chemical atom, the remainder of which is, of course, positively electrified. All electrons are alike, however various the “elements” whence they are derived; as the most minute masses known to science they may be among the primal units of all matter.
France, as well as Germany and England, was to take a leading part in furthering the study of radio-activity. In Paris the famous Becquerel family had for three generations devoted themselves to studying phosphorescence. Henri Becquerel, third of the line, said, “I wonder if a phosphorescent substance, such as zinc sulphide, would be excited by X-rays.” He tried the experiment, causing the sulphide to glow with new vigor. From that moment proofs have accumulated that the rays of common phosphorescence such as are emitted by matches, decaying wood and fish, are of kin to the cathode rays which the electrician evokes from any substance whatever when he employs a high-tension current. One day M. Becquerel came upon a remarkable discovery. He noticed that compounds of uranium, whether phosphorescent or not, affected a photographic plate through an opaque covering of black paper, and rendered the adjacent air an electric conductor. Compounds of thorium, similar to those used for incandescent mantles, were found to have the same properties. And here was detected the cause of an annoyance and loss which had long perplexed photographers. Often they had bestowed sensitive paper or plates within wrappers of stout paper, or card, or thick wood, secluded in dark cupboards or drawers. All in vain. At the end of a few weeks or months these carefully guarded surfaces were as much discolored as if they had been for a few minutes exposed, here and there, to daylight itself. All the while each material relied upon as a safeguard had been sending forth a feeble but constant beam; treachery had lurked in the trusted guardian.
At the suggestion of M. Becquerel, M. and Madame Pierre Curie undertook a thorough quest for these effects in a wide diversity of substances. They found that several minerals containing uranium were more radio-active than that element itself. Pitchblende, for instance, consisting mainly of an oxide of uranium, was especially energetic as it approached an electroscope, suggesting the presence of an uncommonly active constituent, thus far not identified. At the end of a most laborious series of separations they came at last to a minute quantity of radium chloride displaying extraordinary properties. Another compound of radium, a bromide, has since been arrived at: radium by itself has not yet been obtained. In radio-activity radium chloride surpasses uranium about one-million-fold. Provided with an electroscope of exquisite sensibility, Professor Ernest Rutherford of McGill University, Montreal, has discovered seven distinct radiations from radium, each with characteristics of its own. Directed upon plates of aluminium he finds its gamma rays to be 100 times more penetrating than its beta rays, and beta rays 100 times more penetrating than its alpha rays. Each radiation has qualities as distinct as those of an ordinary chemical element. Beta rays behave in all respects like cathode rays, so that here a bridge is discerned betwixt the qualities of radium and the long familiar phenomena of the Crookes tube.
The substance ranking next in radio-activity to radium is thorium. Professor Rutherford has observed it throwing off a substance he calls Thorium X; this radiates strongly for a time, the parent mass not radiating at all. Gradually Thorium X ceases to radiate and the original thorium resumes an emission of Thorium X. From Thorium X emanates what seems a gas, condensible by extreme cold, which attaches itself to adjacent bodies so as to make them radio-active. This emanation in its turn produces successively three new and distinct kinds of radiation. Professor Charles Baskerville, of the College of the City of New York, has separated from thorium two substances probably elementary, carolinium and berzelium.
Other radio-active substances have each several derivatives: actinium has nine, uranium has four. As researchers broaden their range of inquiry they steadily lengthen the list of radio-active substances. Minerals of many kinds, water from springs, especially those of medicinal value, the leaves of plants, newly fallen snow, and even common air, are found to be radio-active, although usually in but a slight degree, so that the doubt may be expressed, Is the observed effect due to a trace of some highly radio-active material diffused in something else which is not radio-active at all? Should it be established that radio-activity is really present in all matter it would be no other than a parallel to what, at another point in the physical scale, presents itself as ordinary evaporation.
Solids are not as Solid as They Seem.
In a northern winter we may observe in air almost still, the wasting away of a large block of ice, so that during a week it loses a considerable part of its bulk. The giving forth of vapor is evidently not restricted to high or to ordinary temperatures, but may occur below the freezing point of water. In 1863, Thomas Graham, the eminent Scottish physicist, from many experiments with metals expressed the opinion that what seems to be a solid may be also in a minute degree both liquid and gaseous as well. Confirmation of this view was afforded in 1886 by Professor W. Spring, of Liege, who formed alloys by strongly compressing their constituents as powders at ordinary temperatures. It is probable that a slight pervasive liquidity gave success to the experiment. Professor Roberts-Austen once observed that an electric-deposit of iron on a clean copper plate adhered so firmly that when they were severed by force, a film was stripped from the copper plate and remained on the iron, signifying that the two metals had penetrated each other at an ordinary temperature. This interpenetration he found to take place through films of electro-deposited nickel. In a remarkable round of experiments he also found that at 100° C., a temperature much below the fusing point of lead, gold as leaf is slightly diffused through a mass of lead; when the lead is fluid at 550° C., the proportion of diffused gold is increased 160,000 times. This volatility of the particles of a heavy metal shows us plainly that virtual evaporation may be always taking place from metallic surfaces at ordinary temperatures,—a phenomenon which may be the same in kind as the pouring out of a perceptible stream of corpuscles under strong electrical excitation. The analogy goes further, at least in the case of liquids, which exhale a vapor usually different in composition from the parent body; take, for example, a solution of sugar in water which sends forth watery vapor only, or observe a mixture of much water and a little alcohol as it emits a vapor largely alcoholic and but slightly aqueous.
Every Property May be Universal.
Here we are reminded of a striking experiment by Faraday: exciting an electro-magnet of gigantic proportions he showed that every substance he brought near to it was affected in a definite degree. He found iron to be pre-eminently magnetic, much as Madame Curie has shown radium to be vastly more radio-active than any other substance. From Faraday’s time to the present hour the whole trend of investigation has built up the probability that every known property in some degree exists in all matter whatever. Copper conducts electricity remarkably well, and gutta percha conducts remarkably ill; but gutta percha has some little conductivity, or thinner sheets of it than those now used would suffice to keep within an ocean cable the throbs which pass between America and Europe. In radio-activity many substances may be as low in the scale as is gutta percha in the list of electric conductors; in that case no existing means of detection would make the property manifest.