Glycerin 0.8 parts is very gradually added,
| producing | C³H⁵O²NO⁴ |  |
| O⁴ | ||
| 2NO⁴ |
From the above extracts of several of the most eminent chemists of the present day, the reader will glean, that in order to prepare this explosive, of uniform quality, invariable in composition, free from water, or any other impurity, it is not merely necessary to buy the best materials, but to have at command the means of verifying their purity before attempting its manufacture.
These points secured, viz: purity and strength of materials, i. e., glycerin free from sugar, fatty acid, saline impurities, and a mixture of Sulphuric Acid with Nitric Acid in due proportion, of due percentage of the respective acids, and not more water therein, nor in the glycerin, at one time of making, than another; the next point to command will be, that in combining the glycerin with the acids, when considerable heat is evolved, the heat thus evolved shall be absorbed rapidly, so as never under any circumstances whatever, to exceed a certain temperature. Sobrero names 32°F; otherwise, according to my experience, very differing nitro-glycerin will result from variation of temperature whilst mixing. Such products may be fatal to the miner, although only affecting the manufacturer in a pecuniary sense. I am led to emphasize these remarks from the fact that prospectuses have been issued to tempt contractors to buy apparatus in the one case, and offering to manufacture on the side of a railroad cutting, if required, in another case, by parties who have no experience in the manufacture, and who start in their new avocation, by deriding the care, outlay and precautions that their competitors have deemed it necessary to make, in order to secure a uniform, certain, and, for mining purposes, perfectly safe explosive; for as the product is to be handed over to the uneducated miner, who cannot estimate the risk he is subjected to even if such a course occurred to him, it does seem to me just and proper, that the controlling engineer, the intelligent contractor, and especially the operating miner who is to handle this explosive, should be advised, that under the term Nitro-Glycerin, very different substances, both as regards explosive force, and liability to spontaneous explosion, do result, unless extraordinary precautions are adopted in the selection of the crude materials, as well as securing uniformly low temperature throughout the process of making. Unless this be done, decomposition sets in and is indicated by the emanation of fumes, by the deepening of the light lemon tint to an orange yellow, and at this point, the miner should decline using it, and require the manufacturer to take his place, and the risks contingent on using it.
Since many of the accidents that have occurred with Nitro-Glycerin, have been traced to leakage from the containing vessel, notably the San Francisco accident, probably the Panama explosion, and undoubtedly the Titusville or Enterprise explosion, besides other cases where it leaked through the bottom of wagon and thence on to the springs, whose hammering caused an explosion, the discovery by Granger, [page 19], confirmed by the magazine explosion, [page 18], teach the importance of transporting this explosive in a solid state, that is, congealed; there is however another reason; decomposing Nitro-Glycerin will not solidify at 45°F, and the consumer has a ready and convenient test for the purity of this article, by seeing to it that he invariably purchases the explosive deliverable in a solid form. Another test is, when exploded, in a close tunnel, the fumes or decomposed gases should not inconvenience the miner.—Failing in either of these tests, it may fairly be rejected as an inferior article, or should be used up as speedily as possible, preferably by the manufacturer or his more experienced employees, rather than by a miner who may not be fully aware of the unnecessary risk to which he is exposed in handling impure Nitro-Glycerin.
METHOD OF ANALYSIS.
Walter Crum[5] describes a method of analysing bodies containing nitric acid, applicable to the nitro-compounds; when nitrate of potash is used, it is previously purified by crystallization, and fused at little more than its melting heat. Nitro-Glycerin, gun-cotton, etc., must be deprived of moisture.
A glass jar eight inches long and an inch and a quarter in diameter, is filled with and inverted over mercury; a single lump of time fused nitrate, weighing about six grains, is let up through the mercury into the inverted jar, and afterwards fifty grains of water. As soon as the nitrate is dissolved, 125 grains of sulphuric acid, ascertained to be free from nitric acid, are added. By the action of the mercury upon the liberated nitric acid, deutoxide of nitrogen soon begins to be evolved, and, usually in about two hours, without the application of heat, the whole of the nitric acid is converted into that gas. Sometimes agitation is necessary, and it is easily performed by giving a jerking horizontal motion to the upper part of the jar. The surface of the sulphuric acid is then marked, and three-fourths of an inch of solution of sulphate of iron recently boiled, let up into the jar. The gas is rapidly absorbed, except a small portion at last, which must be left several hours to the action of the solution, or be well agitated in a smaller tube with a fresh portion of it. No correction of the nitric oxide has to be made for moisture, for the mixture of acid and water employed has no perceptible vapor tension.
In one experiment, 5.40 grains of nitrate of potash yielded 4.975 cubic inches of gas, at 60°F, and barometer 30 inches.
The residue not absorbed by the sulphate of iron, was 0.015 cubic inch, leaving