Something about sugar

by George M. Rolph

The object to be attained in boiling white sugars is the separation of the crystallizable sucrose contained in a given solution from the impurities, moisture and non-crystallizable content of that solution. The formation of sugar crystals is a natural result of the evaporation of the moisture from the liquor or solution. In order to obtain pure white crystals, it is vitally essential that, as far as possible, all impurities and non-sugars, except water, be removed from the liquor before the boiling takes place, for if the coloring matter is not thoroughly taken out, obviously the crystals will be colored. The purifying and decolorizing operation is accomplished in the char filters. After the grain is once formed in definite crystals, these crystals attract and appropriate the sucrose in solution in the process of building up their structure, while repelling or excluding the impurities, so that in consequence the latter remain in solution. Irrespective, however, of whether crystallization of sucrose takes place in solutions of high or low purity, it will only partially remove the sucrose from the solution in one operation, the limit being fixed by the amount and nature of impurities present. In order to bring about further crystallization of sucrose the solution or mother liquor surrounding the crystals must be separated from them and be again diluted, filtered and concentrated.

Briefly, the procedure in boiling white sugar in a vacuum pan is to take liquors of the highest purity for the first boiling. After the first crystals have been removed from the mother liquor in the centrifugal machines, the liquor is again diluted, decolorized by bone-char and boiled to grain. This operation is continued a number of times, the purity of the liquor decreasing each time. Finally, when the purity of the liquor falls to a certain point, the boiling is discontinued, for at this point conditions do not admit of further formation of pure sucrose crystals, and, if the process were pursued further, the resulting sugar would not be white. Therefore, when this state is reached, these low-grade liquors are boiled into a semi-refined sugar, commonly called “refinery raw,” which corresponds fairly closely in test with the original raw sugar, or they are used for making soft yellow sugars as explained later on. This refinery raw is then washed, melted and put through the whole process all over again. The liquor, from which the crystals formed in repeated boilings have been removed as made, at length becomes so charged with impurities that further crystallization of sucrose is impossible and this residue, or final waste, is known as blackstrap molasses.

This manner of boiling white sugar has been called the “out and out” method, in contradistinction to the “in and in” method employed in boiling soft yellow sugars, of which a few words of explanation now follow.

In boiling soft yellow sugars, the aim is to produce a large number of small sucrose crystals having the property of attracting and combining with the molasses content of the liquor and that will retain some of the molasses after they are purged of mother liquor in the centrifugal machines. This process gives a sugar that may be described as a mechanical mixture of sucrose, invert sugar and the non-sugars in the molasses.

In the case of yellow sugars, the lighter the color the better price they bring. The greatest profit, therefore, is derived from the manufacture of sugars of the lightest color and carrying a reduced percentage of sucrose. In boiling such sugars, low-purity liquors from which the coloring matter has been removed as far as practicable by bone-char filtration are required. For the purpose, it is generally found most advantageous to use the liquors taken from white sugar massecuite at the point when, owing to repeated boilings, its purity has fallen so low that further extraction of pure white sucrose crystals is impossible.

As a result of the numerous filtrations through bone-char preparatory to reboiling in the manufacture of white sugar, these liquors are usually lighter in color than any of corresponding purity obtained in the refining process. Nevertheless, they are not necessarily the only liquors suitable for the purpose, and this particularly applies to the making of the lower grades of yellow sugars. It is, however, beyond the scope of this book to elaborate upon that phase of sugar refining. The object sought here is to give a general idea of how yellow sugars are boiled, without going into all the details.

As is the case with white sugars, yellow sugars are made by a succession of boilings in vacuum pans, the liquor used for each boiling or strike being that obtained from the massecuite of the previous strike. The operation is continued until the liquor becomes too low in purity and dark in color. Each successive strike boiled is lower in test than the preceding one, due to the fact that the sucrose crystals represent the purest part of the massecuite, and, consequently, each time they are removed the quality of the liquor is lowered. This accounts for the various grades of yellow sugar that are made, fifteen in all, starting with a creamy white and ending with a dark brown. The sucrose content of the best is about 92 per cent and that of the poorest about 80 per cent.

In making white sugars, the aim is to produce from liquors of high purity sucrose crystals that are pure white, hard and absolutely free from molasses.

In making yellow sugars, the object is to boil from low-purity liquors soft sucrose crystals that possess the property of attracting and retaining the molasses and to make this combination of crystals and molasses as complete as possible.

The essential difference between the two methods, as well as the appropriateness of the descriptive terms “out and out” and “in and in,” will be readily apparent.