Binks bleached oils with oxides of manganese dissolved in the oil, but difficulty was experienced in carefully regulating the quantity of the manganese compounds which were to be introduced into the oil. For instance, he precipitated manganous hydroxide in contact with oil, and added the mixture to the bulk of the material, and he also modified the treatment by dissolving manganous hydroxide in ammonia, and added the solution to the oil.
Hartley and Blenkinsop prepare manganese linoleate, and dissolve this in a hydrocarbon, and add a sufficient quantity of the solution to the oil, whereby it dissolves easily and mixes completely. By this treatment, the colouring matter of the oil forms a compound with the manganese which, while it remains in solution, is very speedily oxidised in contact with air, especially when a current of air or oxygen is blown through. The oxidation destroys the colouring matter, and the manganese compound is deoxidised; subsequently it undergoes oxidation again, and the products of such oxidation taking place in the oil are acrolein, formic and acetic acids. After, or concurrently with, the oxidation of the colouring matters, the oil is oxidised, and, at a suitable temperature below 132° F., the oil is bleached, increased in density, and converted into a pale drying oil. By limiting the amount of the manganese linoleate to that which is capable of just oxidising the colouring matters, oils may be bleached with very little further oxidation.
Excellent drying oils have been produced by this process, of a very pale colour. The oil has been used for decorative house painting, for both indoor and outdoor work, on wood and on metal. It has also been used as a coating for iron work, without the addition of a pigment. The plant used in its production is the same as that employed in oil-boiling by the usual processes when a blast of air is used.
The advantages of a pale boiled oil, containing no lead, are the following:—
1. Zinc white retains its pure white colour.
2. Delicate tints, and colours containing sulphides, are not darkened in course of time.
It may be suggested that for indoor decoration, for the painting of ships, railway carriages, railway semaphores, signs, and stations, such oil is free from liability to alter the colours with which it is mixed, owing to its freedom from lead, which is darkened by traces of sulphuretted hydrogen in the air to which such paints are exposed.
Gasometers in gas-works may be painted an unalterable white with such oil and zinc white. But in this case also the zinc white must be free from lead carbonate or oxide.
In commenting on Prof. Hartley’s paper, Mr. Laurie said he had never used linoleate of manganese for boiling with oil, but by the use of borate one did get a boiled oil paler than the oil with which one started. If you take linseed oil which has been already bleached in the sun to a golden yellow, and convert it into boiled oil with manganese, a further bleaching process undoubtedly takes place. An oil prepared with manganese salts, spread on a glass plate, and allowed to dry in the dark, will remain almost colourless, whereas if it were boiled with a lead salt it quickly darkens, even if it is kept away from impure air. Even in a dark room, in pure air, a picture painted with oil boiled with lead will darken. That is another argument in favour of manganese, and he should say it ought always to be used in preparing oil for artistic purposes.