[26] Travertine, so called from the river Tibur, whose waters are loaded with calcareous earth—Tiburtina, Ital. travertina.
Silicification, or petrifaction by Silex or Flint.—Silex, or the earth of flint, is held in solution in large proportions, in certain thermal or boiling springs, which, on cooling, deposit the siliceous matter (in the same manner as the travertine is precipitated from incrusting streams) on foreign substances, and produce exquisite chalcedonic infiltrations of mosses, &c. But this operation is now only known to be in activity in the immediate neighbourhood of foci of volcanic action, as in the celebrated Geysers of Iceland (Wond. p. 95), and the boiling springs of the volcano of Tongariro, in New Zealand (98). We have everywhere evidence that in former periods, the petrifaction, as well as the incrustation of organic bodies by silex, was carried on to an immense extent; and, doubtless, far beneath the surface, the same operation is at the present moment in constant progress, and effecting as important changes in the consolidation of loose materials, as in the earlier geological epochs.
The various states in which silex occurs have depended on its fluidity; in quartz crystals the solution appears to have been complete; in agate and chalcedony it was in a gelatinous state, assuming a spheroidal or orbicular disposition, according to the motion given to its particles. Its condition appears also to have been modified by the influence of organic matter. In some polished slices of siliceous nodules the transition from flint to agate, chalcedony, and crystallized quartz, is beautifully shown. The curious fact, that the cavities of echinites in chalk are almost invariably filled with flint, while their crustaceous cases are changed into calc-spar, is probably, in many instances, to be attributed to the animal matter having undergone silicification; for the soft gelatinous parts are those which appear to have been most susceptible of this transmutation. In some specimens, the oyster is changed into flint, while the shell is converted into crystallized carbonate of lime. In a Trigonia from Tisbury, formerly in the cabinet of the late Miss Benett, of Norton House, near Warminster, the body of the mollusk was completely metamorphosed into a pure chalcedony, the branchiæ or gills being as clearly defined as when the animal was recent. In specimens of wood from Australia (presented to the British Museum by Sir Thomas Mitchell), which are thoroughly permeated by silex, there are on the external surface some spots of chalcedony that have apparently originated from the exudation of the liquid silex from the interior in viscid globules filled with air, which burst, and then collapsed, and became solidified in their present form.
In silicified wood the permeation of the vegetable tissues by the mineral matter, appears to have been effected by solutions of silex of a high temperature. In some examples the mineralization is simply a replacement: the original substance has been removed atom by atom, and the silex substituted in its place.
One of the most eminent naturalists and chemists of the United States, Mr. Dana,[27] suggests that the reason why silica is so common a material in the constitution of fossil wood and shells, as well as in pseudo-morphic crystals,[28] is the ready solution of silex in water at a high temperature (a fact affirmed by Bergman[29]) under great pressure, whenever an alkali is present, as is seen at the present time in many volcanic regions, and its deposition again when the water cools. A mere heated aqueous solution of silica, under high pressure, is sufficient to explain the phenomenon of the silicification of organic structures. Mr. Dana states that a crystal of calc-spar in such a fluid being exposed to solution, from the action of the heated water alone, the silica deposits itself gradually on a reduction of temperature, and takes the place of the lime, atom by atom, as soon as set free. Every silicified fossil is an example of this pseudo-morphism; but there seems to be no union of the silica with the lime, for silicate of lime is of rare occurrence.[30]
[27] American Journal of Science for January 1845.
[28] Pseudo-morphic crystals are crystals moulded in the cavities left by other crystals which they have replaced. See Dr. Blum on Pseudo-morphous minerals.
[29] Bergman first determined the solubility of silex in simple water, aided by heat, and demonstrated its existence in the Geysers and other boiling springs of Iceland.—Parkinson, Org. Rem. vol. i. p. 324.