In mixed tannages, where the colour is dark, the leather is frequently handled or suspended in a warm sumach or myrobalanes liquor, and occasionally in dilute sulphuric or oxalic acids. If these acids are not effectually removed before drying, the toughness of the leather will be destroyed, and in extreme cases the leather will become brittle and refuse to take black. In any case, strong acids are prejudicial to the durability of the leather. In America, alternate baths of vitriol and sugar of lead are frequently used for bleaching and weighting the leather, but the colour given is not durable.
The great point to aim at, in arranging the mode of work of a tannery, is to contrive that butts should always receive the strongest liquors they can bear with safety, and that the strength should constantly increase in a regular and systematic way. To attain this end, very frequent handling and change of liquor are requisite in the early stages, when the butts rapidly absorb the tannin presented to them. As the process advances, the exterior part of the butt becomes thoroughly tanned, and the liquor only slowly reaches the interior, which is yet susceptible of its action, and hence longer layers in stronger liquors are permissible.
The varied requirements of the trade render it difficult to give any practical information as to the selection of tanning materials. As a general rule, it is important at the outset to give the required colour; and if materials undesirable in this respect are to be used for the sake of cheapness, they should be introduced in the form of liquors in the middle stages of the process, i. e. in the later handlers or earlier layers. Materials used as dust generally have more effect in producing bloom and colouring the leather, than those used in liquors at this stage. Some information as to the respective qualities of the different tanning materials will be found in the chapter on Tannins; but even practical men are very deficient in accurate information on these points, since many materials are never used alone, but invariably in connection with others which mask their effects.
The use of extracts, and the demand for low-priced leathers, to compete with the American tannages, has introduced still more rapid methods than those described, and very fair-looking heavy leather has been tanned in 5-10 weeks. These tannages are very various, but their main feature is the free use of hot liquors, composed principally of extracts and gambier. This treatment imparts great firmness, or more properly speaking, hardness; but the leather is deficient in toughness, and the grain usually cracks on bending sharply. Extract properly used is, however, capable of making excellent leather; it is employed in at least one of the highest priced tannages in the country.
It may be noted here, that when Continental writers speak of extracts and extract tannage, what we should call liquor tannage only is meant, and not specially the use of the concentrated extracts, to which alone in England the term is applied.
[CHAPTER XI.]
SOLE-LEATHER.—Treatment in the Shed.