Blasting Powder.—This is a mixture of 19 parts sulphur, 15 parts charcoal, and 66 parts saltpeter. These powders are made in different size angular polished grains, from the size of a pin head to sizes just passing a ⅜ to ½ inch hole. The larger the grains the slower the action of the powder.
Nitro-Substitution Compounds.—These compounds are formed by the action of nitric acid on hydrocarbons. Triton, T.N.T., or trinitrotoluene, made famous during the war, is an example of these compounds. It is made by the successive nitration of toluene, a coal tar derivative. It melts at 80 degrees C., is very stable, and is of great explosive strength. It is manufactured in a convenient form, being compressed into blocks about 2 inches square by about 4 inches long with a specific gravity of about 1.5. The blocks are usually copper plated to protect the T.N.T. from moisture. The more dense it is the less its sensitiveness. It is also put up in crystalline form in cartridges like dynamite, in which condition it is practically equal to 40 per cent dynamite. It can be cut with a knife, pounded with a hammer, and will burn freely and slowly in small quantities in the open air without exploding. It is suitable for all but the hardest rocks. It creates poisonous gases on detonation which are quickly dissipated in the open air but which render it unsuitable for use in tunnel work.
Nitro-glycerine.—This is formed by the action of nitric and sulphuric acids on animal compounds such as gelatine or glycerine. Nitro-glycerine is a yellowish, oily, highly unstable explosive liquid with a specific gravity of about 1.6. It will burn quietly when ignited in the open air. It will freeze at 41 degrees F., and will explode at 388 degrees F., or on concussion at a lower temperature. It develops about 1,500 times its volume in gas, which due to the heat of combustion is increased to about 10,000 times its volume. It is a very dangerous explosive to handle, and is unsuitable for use in the liquid form.
Blasting Gelatine.—This is made by soaking guncotton in nitro-glycerine. Gelatine dynamite is a combination of blasting gelatine and an absorbent. Forcite is a gelatine dynamite in which the blasting gelatine, forming 50 per cent of the compound, contains 90 per cent nitro-glycerine and 2 per cent guncotton; and the absorbent, forming the other 50 per cent of the compound, contains 76 per cent of sodium nitrate, 3 per cent sulphur, 20 per cent of wood tar, and 1 per cent of wood pulp.
Blasting gelatine is packed in a jelly-like mass in metal lined wooden boxes. It is less sensitive than straight dynamite and is one of the most powerful explosives known. It can be made up to equal 100 per cent dynamite. It is suitable for use in the hardest rocks and for subaqueous work as it is not affected by moisture. It is suitable for use in tunnels as the amount of carbon monoxide, peroxide of nitrogen, hydrogen sulphide and other dangerous gases is comparatively low when fully detonated. Gelatine dynamite[[98]] is sold as 30 per cent to 70 per cent dynamite, the actual percentage of nitro-glycerine being less than the nominal quantity given.
Dynamite.—The dynamites are made by soaking nitro-glycerine in some absorbent. If the absorbent is some neutral substance such as infusorial earth the combination is known as a true dynamite. The false or active dynamites are those in which the absorbent is also an explosive compound. The false dynamites form the best known contractors’ explosives. Among the materials mixed with the nitro-glycerine are: magnesium carbonate, sulphur, wood meal, wood pulp, wood fiber, wood tar, nut galls, kieselguhr, sawdust, resin, pitch, sugar, charcoal, and guncotton. The strength of dynamites is noted by the per cent of nitro-glycerine and nitro substitutes contained. Dualin and Hercules powder both contain 40 per cent nitro-glycerine. Dualin contains 30 per cent sawdust and 30 per cent potassium nitrate, but the Hercules powder, which is stronger, contains 16 per cent sugar, 3 per cent potassium chlorate, 31 per cent potassium nitrate, and 10 per cent magnesium carbonate.
Dynamite is the most common explosive used on construction work. It is supplied in cylindrical sticks wrapped in paper, the diameter of the sticks varying between ⅞ and 2 inches. They are about 8 inches long. Forty per cent dynamite is the common strength found on the market. It is suitable for ordinary work in all but very hard rocks or very soft material. Direct contact with water separates the nitro-glycerine from the base and is dangerous when the explosive is used in wet places unless it is fired immediately after the hole is loaded. It freezes at about 42 degrees F., or at even higher temperatures and in the frozen state it is highly dangerous, requiring powerful detonators for firing, but exploding spontaneously from a slight jar, or the breaking of the stick. Special low-freezing dynamites are made that will not freeze above 35 degrees F.
Ammonia Compounds.—Ammonia dynamite is a combination of nitro-glycerine, ammonium nitrate and such other ingredients as sodium nitrate, calcium carbonate and combustible material. This form of explosive is advantageous for underground work because, like gelatine dynamite, its explosion does not create large quantities of poisonous gases. It has a low freezing point and is relatively low in cost. It is seriously affected by moisture, however, and can not be used in wet places. Ammonium nitrate explosives which do not contain nitro-glycerine include 70 per cent to 95 per cent ammonium nitrate and some combustible material. Ammonal is a special type of this class formed by a mixture of ammonium nitrate, aluminum, and triton. All of these explosives are deliquescent, insensitive to shock, and are cheaper than the dynamites.
173. Permissible Explosives.—As specified by the United States Bureau of Mines explosives whose rapidity, detonation, and temperature of explosion will not ignite explosive mixtures of pit gases and air are known as permissible explosives. They include nitrate explosives, ammonia dynamite, and others.
Gunpowder, triton, picric acid, blasting gelatine, dynamite, guncotton, etc., are not classed as permissible explosives.