Fixed solids are reported as the difference between the total and volatile solids. They are therefore representative of the amount of inorganic matter present.
Suspended matter is the undissolved portion of the total solids. High volatile suspended matter is an indication of offensive qualities in the nature of putrefying organic matter, whereas fixed suspended matter is indicative of inoffensive inorganic matter. It is difficult to obtain a sample of sewage which will represent the amount of suspended matter in the sewage, since a sample taken from near the surface will contain less inorganic matter and grit than a sample taken near the bottom.
Settling solids are indicative of the sludge forming properties of the sewage and of the probable degree of success of treatment by plain sedimentation. Volatile settling solids indicate the property of the formation of offensive putrefying sludge banks. There is no chemical test which will indicate the scum-forming properties of sewage. Fixed settling solids indicate the presence of inorganic matter, probably gritty material such as sand, clay, iron oxide, etc.
Colloidal matter is material which is too finely divided to be removed by filtration or sedimentation, yet is not held in solution. It can sometimes be removed by violent agitation in the presence of a flocculent precipitate, as in the treatment with activated sludge, or by the flocculent precipitate alone, as in chemical precipitation, or by the acidulation of the sewage so as to precipitate the colloids. Colloidal matter is probably the result of the constant abrasion of finely divided suspended matter while flowing through the sewer or other channel. High colloidal matter may therefore indicate a stale sewage, or the presence of a particular trades waste. Colloids are difficult of removal. For this reason, where sewage is to be treated, turbulence in the tributary channels should be avoided.
Alkalinity may indicate the possibility of success of the biologic treatment of sewage, since bacterial life flourishes better in a slightly alkaline than in a slightly acid sewage. Within the normal limits of the amount of alkalinity in sewage the exact amount has little significance in sewage analyses. Sewages are normally slightly alkaline. An abnormal alkalinity or acidity may indicate the presence of certain trades wastes necessitating special methods of treatment. A method of sewage treatment may be successful without changing the amount of alkalinity in the sewage since the amount of alkalinity is not inherently an objection.
Chlorine, in the form of sodium chloride, is an inorganic substance found in the urine of man and animals. The amount of chlorine above the normal chlorine content of pure waters in the district is used as an index of the strength of the sewage. The chlorine content may be affected by certain trades wastes such as ice-cream factories, meat-salting plants, etc., which will increase the amount of chlorine materially. Since chlorine is an inorganic substance which is in solution it is not affected by biological processes nor sedimentation. Its diminution in a treatment plant or in a flowing stream is indicative of dilution and the reduction of chlorine will be approximately proportional to the amount of dilution.
Fats have a recoverable market value when present in sufficient quantity to be skimmed off the surface of the sewage. Ordinarily fats are an undesirable constituent of sewage as they precipitate on and clog the interstices in filtering material, they form objectionable scum in tanks and streams, and they are acted on very slowly by biological processes of sewage treatment. Although fats are carbonaceous matter they are not indicated by the oxygen consumed test because they are not easily oxidized. They are therefore determined in another manner; by evaporation of the liquid and extracting the fats from the residue by dissolving them in ether.
Relative stability and bio-chemical oxygen demand are the most important tests indicating the putrefying characteristics of sewage. Since stability and putrescibility have opposite meanings the relative stability test is sometimes called the putrescibility test. The relative stability of a sewage is an expression for the amount of oxygen present in terms of the amount required for complete stability.
A relative stability of 75 signifies that the sample examined contains a supply of available oxygen equal to 75 per cent of the amount of oxygen which it requires in order to become perfectly stable. The available oxygen is approximately equivalent to the dissolved oxygen plus the available oxygen of nitrate and nitrite.[[125]]
| TABLE 72 | |
|---|---|
| Relative Stability Numbers | |
| Time Required for Decolorization at 20° C. Days | Relative Stability Number |
| 0.5 | 11 |
| 1.0 | 21 |
| 1.5 | 30 |
| 2.0 | 37 |
| 2.5 | 44 |
| 3.0 | 50 |
| 4.0[[126]] | 60 |
| 5.0 | 68 |
| 6.0 | 75 |
| 7.0 | 80 |
| 8.0 | 84 |
| 9.0 | 87 |
| 10.0 | 90 |
| 11.0 | 92 |
| 12.0 | 94 |
| 13.0 | 95 |
| 14.0 | 96 |
| 16.0 | 97 |
| 18.0 | 98 |
| 20.0 | 90 |