Tubes are placed directly above these wire terminals in the vat, one tube being over each electrode and separated from each other by some distance. With the passage of an electric current from one wire terminal to the other, bubbles of gas rise from each and pass into the tubes. The gas that comes from the negative terminal is hydrogen and that from the positive pole is oxygen, both gases being almost pure if the work is properly conducted. This method produces electrolytic oxygen and electrolytic hydrogen.
The Liquid Air Process.--While several of the foregoing methods of securing oxygen are successful as far as this result is concerned, they are not profitable from a financial standpoint. A process for separating oxygen from the nitrogen in the air has been brought to a high state of perfection and is now supplying a major part of this gas for oxy-acetylene welding. It is known as the Linde process and the gas is distributed by the Linde Air Products Company from its plants and warehouses located in the large cities of the country.
The air is first liquefied by compression, after which the gases are separated and the oxygen collected. The air is purified and then compressed by successive stages in powerful machines designed for this purpose until it reaches a pressure of about 3,000 pounds to the square inch. The large amount of heat produced is absorbed by special coolers during the process of compression. The highly compressed air is then dried and the temperature further reduced by other coolers.
The next point in the separation is that at which the air is introduced into an apparatus called an interchanger and is allowed to escape through a valve, causing it to turn to a liquid. This liquid air is sprayed onto plates and as it falls, the nitrogen return to its gaseous state and leaves the oxygen to run to the bottom of the container. This liquid oxygen is then allowed to return to a gas and is stored in large gasometers or tanks.
The oxygen gas is taken from the storage tanks and compressed to approximately 1,800 pounds to the square inch, under which pressure it is passed into steel cylinders and made ready for delivery to the customer. This oxygen is guaranteed to be ninety-seven per cent pure.
Another process, known as the Hildebrandt process, is coming into use in this country. It is a later process and is used in Germany to a much greater extent than the Linde process. The Superior Oxygen Co. has secured the American rights and has established several plants.
Oxygen Cylinders.--Two sizes of cylinders are in use, one containing 100 cubic feet of gas when it is at atmospheric pressure and the other containing 250 cubic feet under similar conditions. The cylinders are made from one piece of steel and are without seams. These containers are tested at double the pressure of the gas contained to insure safety while handling.
One hundred cubic feet of oxygen weighs nearly nine pounds (8.921), and therefore the cylinders will weigh practically nine pounds more when full than after emptying, if of the 100 cubic feet size. The large cylinders weigh about eighteen and one-quarter pounds more when full than when empty, making approximately 212 pounds empty and 230 pounds full.
The following table gives the number of cubic feet of oxygen remaining in the cylinders according to various gauge pressures from an initial pressure of 1,800 pounds. The amounts given are not exactly correct as this would necessitate lengthy calculations which would not make great enough difference to affect the practical usefulness of the table:
Cylinder of 100 Cu. Ft. Capacity at 68° Fahr.
Gauge Volume Gauge Volume
Pressure Remaining Pressure Remaining
1800 100 700 39
1620 90 500 28
1440 80 300 17
1260 70 100 6
1080 60 18 1
900 50 9 1/2
Cylinder of 250 Cu. Ft. Capacity at 68° Fahr.
Gauge Volume Gauge Volume
Pressure Remaining Pressure Remaining
1800 250 700 97
1620 225 500 70
1440 200 300 42
1260 175 100 15
1080 150 18 8
900 125 9 1-1/4