The radius of a molecule, considered as a sphere, is of the order of magnitude 0·1 μμ, where μμ means 10⁻⁶ millimetre or 0·001 micron. Even if a molecule is by no means a rigid sphere, the value given shows that the molecule is almost unbelievably small, or, in other words, that it can produce appreciable attraction and repulsion in only a very small region in space.
The number of molecules in a cubic centimetre of gas at 0° C. and atmospheric pressure has been calculated with fair accuracy as approximately 27 × 10¹⁸. From this number and from the weight of a cubic centimetre of a given gas the weight of one molecule can be found. One hydrogen molecule weighs about 1·65 × 10⁻²⁴ grams, and one gram of hydrogen contains about 6 × 10²³ atoms and 3 × 10²³ molecules. The weight of the atoms of the other elements can be found by multiplying the weight of the hydrogen atom by the relative atomic weight of the element in question—16 for oxygen, 14 for nitrogen, etc. If the pressure on the gas is reduced as much as possible (to about one ten-millionth of an atmosphere) there will still be 3 × 10¹² molecules in a cubic centimetre, and the average distance between molecules will be about one micron. The mean free path between two collisions will be considerable, about two metres, for instance, in the case of hydrogen.
The values found for the number, weight and dimensions of molecules are either so very large or so extremely small that many people, instead of having more faith in the atomic and molecular theory, perhaps may be more than ever inclined to suppose the atoms and molecules to be mere creations of the imagination. In fact, it is only two or three decades ago that some physicists and chemists—led by the celebrated German scientist, Wilhelm Ostwald—denied the existence of atoms and molecules, and even went so far as to try to remove the atomic theory from science. When these sceptics, in defence of their views, said that the atoms and molecules were, and for ever would be, completely inaccessible to observation, it had to be admitted at that time that they were seemingly sure of their argument, in this one objection at any rate.
A series of remarkable discoveries at the close of the nineteenth century so increased our knowledge of the atoms and improved the methods of studying them that all doubts about their existence had to be silenced. However incredible it may sound, we are now in a position to examine many of the activities of a single atom, and even to count atoms, one by one, and to photograph the path of an individual atom. All these discoveries depend upon the behaviour of atoms as electrically charged, moving under the influence of electrical forces. This subject will be developed in another section after a discussion of some phenomena of light, an understanding of which is necessary for the appreciation of the theory of atomic structure proposed by Niels Bohr.
In the molecular theory of gases, where we have to do with neutral molecules, much progress has in the last years been made by the Dane, Martin Knudsen, in his experiments at a very low pressure, when the molecules can travel relatively far without colliding with other molecules. While his researches give information on many interesting and important details, his work gives at the same time evidence of a very direct nature concerning the existence of atoms and molecules.
CHAPTER II
LIGHT WAVES AND THE SPECTRUM
The Wave Theory of Light.
There have been several theories about the nature of light. The great English physicist, Isaac Newton (1642-1727), who was a pioneer in the study of light as well as in that of mechanics, favoured an atomic explanation of light; i.e., he thought that it consisted of particles or light corpuscules which were emitted from luminous bodies like projectiles from a cannon. In contrast to this “emission” theory was the wave theory of Newton’s contemporary, the Dutch scientist, Huygens. According to him, light was a wave motion passing from luminous bodies into a substance called the ether, which filled the otherwise empty universe and permeated all bodies, at least all transparent ones. In the nineteenth century the wave theory, particularly through the work of the Englishman, Young, and the Frenchman, Fresnel, came to prevail over the emission theory. Since the wave theory plays an important part in the following chapters, a discussion of the general characteristics of all wave motions is appropriate here. The examples will include water waves on the surface of a body of water, and sound waves in air.
Fig. 4.—Photograph of the interference between two similar wave systems.