When light passes from one medium to another, as from air to glass or vice versa, it is refracted, i.e., the direction of the light rays is changed; but if the light is composed of different colours the refraction is accompanied by a “spreading” of the colours which is called dispersion. If we look through a glass prism so that the light from the object examined must pass in and out through two faces of the prism which make not too great an angle with each other, the light-producing object is not only displaced by the refraction, but has coloured edges. Newton was the first to explain the relation of the production of the colours to refraction. He made an experiment with sunlight, which he sent through a narrow opening into a dark room. The sunlight was then by a glass prism transformed or dispersed into a band of colour, a spectrum consisting of all the colours of the rainbow, red, yellow, green, blue and violet, in the order named, and with continuous transition stages between neighbouring colours.
Fig. 9.—Prism spectroscope. To the right is seen the collimator,
to the left the telescope, in the foreground a scheme for
illuminating the cross-wire.
(From an old print.)
In Newton’s original experiment the different wave-lengths were but imperfectly separated. A spectrum with pure wave-lengths can be obtained with a spectroscope ([cf. Fig. 9]). The light to be investigated illuminates an adjustable vertical slit in one end of a long tube, called the collimator, with a lens in the other end. If the slit is in the focal plane of the lens, the light at any point in the slit goes in parallel rays after meeting the lens. It then meets a prism, with vertical edges, placed on a little revolving platform. The rays, refracted by the prism, go in a new direction into a telescope whose objective lens gives in its focal plane, for every colour, a clear vertical image of the slit. These images can be examined through the ocular of the telescope; but since the different colours are not refracted equally, each coloured image of the slit has its own place. The totality of the slit images then forms a horizontal spectrum of the same height as the individual images. By revolving the collimator different parts of the spectrum can be put in the middle of the field of view. To facilitate measurements in the spectrum there is in the focal plane of the collimator a sliding cross-wire with an adjusting screw or a vertical strand of spider web.
Fig. 10.—The mode of operation of a grating.
A, grating; C, D, E ... H, slits; M M, incident rays. When D D′, E E′ ... are a whole number of wave-lengths, the light waves which move in the direction indicated by C N and are collected by a lens, at the focal point will all be in the same phase and therefore will reinforce each other. In other directions the light action from one slit is compensated by that from another.
Instead of using the refraction of light in a prism to separate the wave-lengths, we can use the interference which arises when a bundle of parallel light waves passes through a ruled grating, consisting of a great many very fine parallel lines, equidistant from each other; such a grating can be made by ruling lines with a diamond point on the metal coating of a silvered plate of glass. From each line there are sent out light waves in all directions; but if we are considering light of one definite colour (a given wave-length, monochromatic light), the interference among the waves from all the slits practically destroys all waves except in the direction of the original rays and in the directions making certain angles with the former, dependent upon the wave-length and the distance between two successive lines (the grating space). Monochromatic light can be obtained by using as the source of light a spirit flame, coloured yellow with common salt (sodium chloride). If the slit in a spectroscope is lighted with a yellow light from such a flame, and if a grating normal to the direction of the rays is substituted for the prism, then in the telescope there is seen a yellow image of the slit, and on each side of it one, two, three or more yellow images. If sunlight is used the central image is white, since all the colours are here assembled. The other images become spectra because the different colours are unequally refracted. In these grating spectra, which according to their distance from the central line are called spectra of the first, second or third order, the violet part lies nearest to the central line, the red part farthest away. Since the deflection is the greater the greater the wave-length, then violet light must have the shortest wave-length and red the greatest. From the amount of the refraction and the size of the grating space the wave-length of the light under investigation can be calculated.
For the yellow light from our spirit flame the wave-length is about 0·000589 mm. or 0·589 μ or 589 μμ. In centimetres the wave-length is 0·0000589 cm.; from the formula ν = c/λ, ν = 526 × 10¹². The frequency is thus almost inconceivably large. For the most distant red and violet in the spectrum the wave-lengths are respectively about 800 μμ and 400 μμ, and the frequencies 375 × 10¹² and 750 × 10¹² oscillations per second.