As mentioned above, one atom of oxygen combines with two atoms of hydrogen to form water, while one atom of chlorine combines with but one atom of hydrogen to form hydrogen chloride. The oxygen atom thus seems to be “equivalent” to two hydrogen atoms or two chlorine atoms, while one chlorine atom is “equivalent” to one hydrogen atom. The atoms of hydrogen and chlorine are for this reason called monovalent, while that of oxygen is called divalent. Again an acid is a chemical compound containing hydrogen, in which the hydrogen can be replaced by a metal to produce a metallic salt. Thus, when zinc is dissolved by sulphuric acid to form hydrogen and the salt zinc sulphate, the hydrogen of the acid is replaced by the zinc and the chemical change may be expressed by the formula
Zn+H₂SO₄ ⇾ H₂+ZnSO₄
In this, one atom of zinc changes place with two atoms of hydrogen. The zinc atom is therefore divalent. This is consistent with the fact that one zinc atom will combine with one oxygen atom to form zinc oxide. To take another example, if silver is dissolved in nitric acid, one atom of silver is exchanged for one atom of hydrogen. Silver, therefore, is monovalent, and we should expect that one atom of oxygen would unite with two atoms of silver. Some elements are trivalent, as, for example, nitrogen, which combines with hydrogen to form ammonia, NH₃; others, again, are tetravalent, such as carbon, which unites with hydrogen to form marsh gas CH₄, and with oxygen to form carbon dioxide CO₂. A valence greater than seven or eight has not been found in any element.
Fig. 3.—Rough illustrations of the valences of the elements.
A. Hydrogen chloride (HCl); B. Water (H₂O); C. Methane (CH₄); D. Ethylene (C₂H₄).
If we consider the matter rather roughly and more or less as Gassendi did, we can explain the concept of valence by assuming that the atoms possess hooks; thus hydrogen and chlorine are each furnished with one hook, oxygen and zinc with two hooks, nitrogen with three hooks, etc. When a hydrogen atom and a chlorine atom are hooked together, there are no free hooks left, and consequently the compound is said to be saturated. When one hydrogen atom is hooked into each of the hooks of an oxygen or carbon atom the saturation is also complete ([see Fig. 3, A, B, C]).
The matter is not so simple as this, however, since the same element can often appear with different valences. Iron may be divalent, trivalent or hexavalent in different compounds. In many cases, however, where an examination of the weight ratios seems to show that an element has changed its valence, this is not really true. It was mentioned previously that carbon forms another compound with hydrogen in addition to CH₄, namely, ethylene, containing half as much hydrogen in proportion to the same amount of carbon. With the aid of Avogadro’s Law, it is found that the ethylene molecule is not CH₂ but C₂H₄. Thus we can say that the two carbon atoms in the molecule are held together by two pairs of hooks, and consequently the compound can be expressed by the formula
| H - C - H |
| | | |
| H - C - H |
where the dashes correspond to hooks ([cf. Fig. 3, D]). Such a formula is called a structural formula.