Rust on Stripped Graphite Film
Section of Wire Painted with a Stimulative Carbonaceous Paint
Corroded and Pitted Surface of Plate Painted with Stimulative Paint
The longevity of lampblack and carbon black paint films when applied to wood has been attributed to the slow drying nature of these pigments when mixed with oil. It is assumed that they have the property of keeping the oil in a semi-drying condition, which will not disintegrate as early as when the oil is thoroughly dried to linoxyn. If this is true, it would seem advisable to use with hard-drying pigments, a proportion of some oil that is semi-drying in nature or one which will leave a film not too hard. Soya bean oil, wood oil, and fish oil present themselves as candidates for such use. How they will work in practice, however, is a question not yet determined. On the other hand, it is well known that these pigments require enormous quantities of oil in order to grind to a working consistency, and it is possible that the life of such coatings is due rather to the property of these pigments, of taking up large quantities of oil, than to their effect upon the slow drying of oil. Excessive oil carrying, however, should be avoided, as shown by the early failure and pitting of those carbon black and lampblack paints ground with very large quantities of oil, as is the usual practice. When these carbon and lampblack pigments were ground with barytes (which is a heavy pigment and requires only about 9 pounds of oil to 100 pounds of pigment, as against 175 pounds of oil to 100 pounds of lampblack), it was found that the lampblack and carbon black paints were reinforced and made more suitable for actual practice. The stimulative nature of these black pigments, however, asserted itself in both cases, and large pittings and eruptions were evident at the end of a year. Carbon black, lampblack, graphite, or any other good conductor of electricity should never be placed next to the surface of iron. They are good as top-coatings, but not as prime-coaters. Some pigments are stimulators of corrosion, because they contain water-soluble impurities that hasten the rusting, while others, like graphite, hasten it simply because, being good conductors, they stimulate surface electrolysis.
Panel No. 20—Willow Charcoal. In excellent condition throughout. Presence of small quantities of potash may be responsible for the inhibitive nature of this black pigment.