The History and Practice of the Art of Photography

by Henry Hunt Snelling

Distilled Water.--All the water used, both for mixing the solutions, washing the paper, or cleaning the brushes, must be distilled, to obtain good results, for reasons before specified.

Blotting Paper.--In many instances, the prepared paper requires to be lightly dried with bibulous paper. The best description is the white sort. In each stage of the preparation distinct portions of bibulous paper must be used. If these be kept seperate and marked, they can be again employed for the same stage; but it would not do, for example, to dry the finished picture in the same folds in which the sensitive paper had been pressed. A very convenient method is to have two or three quarto size books of bibulous paper, one for each seperate process.

Nitrate of Silver.--In the practice of the photographic art, much depends on the nitrate of silver. Care should be taken to procure the best; the crystalized salt is most suitable for the purpose. While in the form of crystal it is not injured by exposure to light, but the bottles containing the solutions of this salt should at all times be kept wrapped in dark paper, and excluded from daylight.

II. DIFFERENT METHODS OF PREPARING THE PAPER.--Preparation of the Paper.--Dip the paper to be prepared into a weak solution of common salt. The solution should not be saturated, but six or eight times diluted with water. When perfectly moistened, wipe it dry with a towel, or press it between bibulous paper, by which operation the salt is uniformly dispersed through its substance. Then brush over it, on one side only, a solution of nitrate of silver. The strength of this solution must vary according to the color and sensitiveness required. Mr. Talbot recommends about fifty grains of the salt to an ounce of distilled water. Some advise twenty grains only, while others say eighty grains to the ounce. When dried in a dark room, the paper is fit for use. To render this paper still more sensitive, it must again be washed with salt and water, and afterwards with the same solution of nitrate of silver, drying it between times. This paper, if carefully made, is very useful for all ordinary photographic purposes. For example, nothing can be more perfect than the images it gives of leaves and flowers, especially with a summer's sun; the light, passing through the leaves, delineates every ramification of their fibres. In conducting this operation, however, it will be found that the results are sometimes more and sometimes less satisfactory, in consequence of small and accidental variations in the proportions employed. It happens sometimes that the chloride of silver formed on the surface of the paper is disposed to blacken of itself, without any exposure to light. This shows that the attempt to give it sensibility has been carried too far. The object is, to approach as nearly to this condition as possible without reaching it; so that the preparation may be in a state ready to yield to the slightest extraneous force, such as the feeblest effect of light.

Cooper's Method.--Soak the paper in a boiling hot solution of chlorate of potash (the strength matters not) for a few minutes; then take it out, dry it, and wet it with a brush, on one side only, dipped in a solution of nitrate of silver, sixty grains to an ounce of distilled water, or, if not required to be so sensitive, thirty grains to the ounce will do. This paper possesses a great advantage over any other, for the image can be fixed by mere washing. It is, however, very apt to become discolored even in the washing, or shortly afterwards, and is, besides, not so sensitive, nor does it become so dark as that made according to Mr. Talbot's method.

Daguerre's Method.--Immerse the paper in hydrochloric (or as it is more commonly called, muriatic) ether, which has been kept sufficiently long to become acid; the paper is then carefully and completely dried, as this is essential to its proper preparation. It is then dipped into a solution of nitrate of silver, and dried without artificial heat in a room from which every ray of light is carefully excluded. By this process it acquires a very remarkable facility in being blackened on a very slight exposure to light, even when the latter is by no means intense. The paper, however, rapidly loses its extreme sensitiveness to light, and finally becomes no more impressionable by the solar beams than common nitrate paper.

Bromide Paper.--Of all common photographic paper, the best, because the least troublesome in making, and the most satisfactory in result, is that which is termed bromine paper, and which is thus prepared:--Dissolve one hundred grains of bromide of potassium in one ounce of distilled water, and soak the paper in this solution. Take off the superfluous moisture, by means of your bibulous paper, and when nearly dry, brush it over on one side only, with a solution of one hundred grains of nitrate of silver to an ounce of distilled water. The paper should then be dried in a dark room, and, if required to be very sensitive, should a second time be brushed over with the nitrate of silver solution.

In preparing the papers mentioned above, there are two circumstances which require particular attention. In the first place, it is necessary to mark the paper on the side spread with the solutions of nitrate of silver, near one of the extreme corners. This answers two purposes: in the first place it serves to inform the experimentalist of the sensitive surface; and secondly, it will be a guide as to which portion of the papers has been handled during the application of the solution, as the impress of the fingers will probably come out upon the photograph. The second caution is, that the application of the sensitive solution (nitrate of silver,) and the subsequent drying of the paper, must be always conducted in a perfectly dark room, the light of a candle alone being used.

III. PHOTOGENIC PROCESS ON PAPER.--Method.--The simplest mode is to procure a flat board and a square of glass, larger in size than the object intended to be copied. On the board place the photographic paper with the prepared side upwards, and upon it the object to be copied; over both lay the glass and secure them so that they are in close connection by means of binding screws or clamps, similar to g. g. fig. 29. Should the object to be copied be of unequal thickness, such as a leaf, grass, &c., it will be necessary to place on the board, first, a soft cushion, which may be made of a piece of fine flannel and cotton wool. By this means the object is brought into closer contact with the paper, which is of great consequence, and adds materially to the clearness of the copy. The paper is now exposed to diffused daylight, or, still better, to the direct rays of the sun, when that part of the paper not covered by the object will become tinged with a violet color, and if the paper be well prepared, it will in a short time pass to a deep brown or bronze color. It must then be removed, as no advantage will be obtained by keeping it longer exposed; on the contrary, the delicate parts yet uncolored will become in some degree affected. The photogenic paper will now show a more or less white and distinct representation of the object. The apparatus figured at 29 consists of a wooden frame similar to a picture frame; a piece of plate glass is fixed in front; and it is provided with a sliding cover of wood, c., which is removed when the paper is ready to be exposed to the action of the light. The back, d., which is furnished with a cushion, as just described, is made to remove for the purpose of introducing the object to be copied, and upon it the prepared paper; the back is then replaced, and, by aid of the cross piece and screw, e., the whole is brought into close contact with the glass.