Of the gases given off by explosives, those resulting from black powder are accompanied by considerable odor and smoke, and, consequently, the miners go back more slowly after the shots, allowing time for the gases to be dissipated by the ventilation. With the permissible explosive, the miner, seeing no smoke and observing little odor, is apt to be incautious, and to think that he may run back immediately. As more is learned of the use of these explosives, this source of danger, which is, however, inconsiderable, will be diminished. Table 1 gives the percentages of the gaseous products of combustions from equal weights of black powder and two of the permissible explosives. Of the latter, one represents the maximum amount of injurious gases, and the other the minimum amount, between which limits the permissible explosives approximately vary.
Such noxious gases as may be produced by the discharge of the explosive are diluted by a much larger volume of air, and are practically harmless, as proven by actual analysis of samples taken at the face immediately after a discharge.
TABLE 1.
| Black powder. | Permissible Explosives. | ||
|---|---|---|---|
| Maximum. | Minimum. | ||
| CO2 | 22.8 | 14.50 | 21.4 |
| CO | 10.3 | 27.74 | 1.3 |
| N | 10.3 | 45.09 | 74.4 |
In addition to investigations as to explosives for use in coal mining, the Explosives Section of the Geological Survey analyzes and tests all such materials, fuses, caps, etc., purchased by the Isthmian Canal Commission, as well as many other kinds used by the Government. It is thus acquiring a large fund of useful information, which will be published from time to time, relative to the kinds of explosives
and the manner of using them best suited to any blasting operations, either above or under water, in hard rock, earth, or coal. There has been issued from the press, recently, a primer of explosives,[7] by Mr. Clarence Hall, the engineer in charge of these tests, and Professor C. E. Munroe, Consulting Explosives Chemist, which contains a large amount of valuable fundamental information, so simply expressed as to be easily understandable by coal miners, and yet sufficiently detailed to be a valuable guide to all persons who have to handle or use explosives.
In the first chapters are described the various combustible substances, and the chemical reactions leading to their explosibility. The low and high explosives are differentiated, and the sensitiveness of fulminate of mercury and other detonators is clearly pointed out. The various explosives, such as gunpowder, black blasting powder, potassium chlorate powders, nitro-glycerine powders, etc., are described, and their peculiarities and suitability for different purposes are set forth. The character and method of using the different explosives, both in opening up work and in enclosed work in coal mines, follow, with information as to the proper method of handling, transporting, storing, and thawing the same. Then follow chapters on squibs, fuses, and detonators; on methods of shooting coal off the solid; location of bore-holes; undercutting; and the relative advantages of small and large charges, with descriptions of proper methods of loading and firing the same. The subjects of explosives for blasting in rock, firing machines, blasting machines, and tests thereof, conclude the report.
The work of the chemical laboratory in which explosives are analyzed, and in which mine gases and the gases produced by combustion of explosives and explosions of coal-gas or coal dust are studied, has been of the most fundamental and important character. The Government is procuring a confidential record of the chemical composition and mode of manufacture of all explosives, fuses, etc., which are on the market. This information cannot but add greatly to the knowledge as to the chemistry of explosives for use in mines, and will furnish the basis on which remedial measures may be devised.
A bulletin (shortly to go to press) which gives the details of the physical tests of the permissible explosives thus far tested, will set
forth elaborately the character of the testing apparatus, and the method of use and of computing results.[8]