Methods of Use.—The synthetic tanning materials may be put to many uses. When well manufactured they make practically a white leather, and this fact makes a valuable opening for their use in connection with light leather tannages and the dressing of rugs. It is also claimed that they improve the colour usually obtained in the ordinary vegetable tannages. If used in the suspenders to the extent of 5-10 per cent. they are said to brighten the colour throughout the tannage. If used in bleaching and finishing they are said to lighten the colour of the finished leather. About 5 per cent. on the weight of the goods may be added to the bleach or vat liquors; they may be also mixed with sumac during finishing, and in effect act as a sumac substitute; solutions are also brushed over the grain before oiling, with a view to obtaining good colour. It is also claimed that their use prevents vegetable-tanned leather from becoming red under the action of sunlight. The syntans are also used to lighten the colour of chrome leather, even of chrome sole leather after it has been dipped.

It is claimed also that syntans produce a tough leather, and if used for heavy leather in the early stages they give a tough grain and assist in avoiding a cracky grain. On this account they are also recommended for re-tanning E.I. tanned kips. When used in heavy leather suspenders they are said to get rid of lime blast (CaCO3) and to quicken the tannage, i.e. to enable the same weight to be obtained in less time. Procter suggests that a tannage of commercial value might be obtained by blending them with wood pulp extract.

If used alone for tanning a series of pits containing liquors of 4° to 37° Bkr. may be used, but drum tannages may be given using liquors of 14°-29° Bkr., the goods being tanned in 6-8 hours. About 30 per cent. of syntans are said to be necessary for complete tannage.

REFERENCES.
E. Stiasny, "A New Synthetic Tannin," Collegium, 1913, 142-145. (See also J.S.C.I., Abs. 1913, 500.)
E. Stiasny, "Syntans—New Artificial Tanning Materials," J.S.C.I., 1913, 775.
Patents:—
Austrian 58,405.
German 262,558, Sept. 12, 1911.
French 451,875, Dec. 13, 1912; 451,876, Dec. 13, 1912; 451,877, Dec. 13, 1912.

SECTION VI.—COMBINATION TANNAGES

The formation of leather being due to the adsorption of colloidogenic substances at the interface of the tanning liquor and the hide gel, there is the obvious possibility that several such substances may be used simultaneously, and that the resulting leather may be due to the combined effect of these substances. Indeed, the average vegetable tannage consists of such a combination tannage, each tanning material contributing its own individual tannin and characteristic astringent non-tannins. There is evidently also the possibility that the different types of tannage discussed above might be used either simultaneously or successively, and that a leather might be obtained which combines to some extent the qualities of each of the types in combination. It is such a case that is generally called a "combination tannage." There are many conceivable combinations, and in this section will be chiefly discussed a few which have demonstrated some commercial possibilities. Some of these have already received notice in the preceding sections. The manufacture of curried dressing leathers is a combination of vegetable and fat tannages. The manufacture of waterproof chrome uppers illustrates a combination of chrome and fat tannages. The use of "syntans" in conjunction with vegetable tanning materials is also a combination tannage. The case of chamois leather is possibly a combination of aldehyde tannage with fatty acid tannage. Two-bath chrome leather is a combination of chrome, sulphur and fat tannage. Formaldehyde and vegetable tannage is also a known possibility. It is clear that there are possibilities of endless complexity, and that what normally may appear as a simple tannage is in reality a very complex combination tannage. From this standpoint one might instructively consider the successive adsorptions involved in a goatskin tanned first with syntans, then with oak bark, "retanned" in sumac, mordanted with chrome, dyed with coal-tar dyestuffs and finally oiled with linseed oil. It will be easily seen that in a very strict sense nearly all tannages are combinations.

Usually, however, the term "combination tannage" is confined to those cases where the main tanning agents not only differ in type, but where none are in predominant quantity. A typical case is that of "semichrome leather," in which a vegetable tannage is succeeded by a chrome tannage. E.I. tanned sheep and goat skins are rather heavily "stripped" of their vegetable tannage and heavy oiling, by drumming with warm soda solutions, and after washing with water are chromed with the one-bath process; they are neutralized, dyed, fat liquored and finished for glacé upper leather.

In a precisely similar way kips and split hides which have received vegetable tannage are stripped and retanned in chrome and finished as for box calf, of which they are a good imitation. Such vegetable-chrome combination tannages possess many of the properties of chrome leather.

To chrome the pelt first and afterwards to subject it to vegetable tannage is also an obvious possibility, but has not yet been made a commercial success in this country, but has been increasingly used in the U.S.A. during the War.