Obs. 17. If a Bubble be blown with Water first made tenacious by dissolving a little Soap in it, 'tis a common Observation, that after a while it will appear tinged with a great variety of Colours. To defend these Bubbles from being agitated by the external Air (whereby their Colours are irregularly moved one among another, so that no accurate Observation can be made of them,) as soon as I had blown any of them I cover'd it with a clear Glass, and by that means its Colours emerged in a very regular order, like so many concentrick Rings encompassing the top of the Bubble. And as the Bubble grew thinner by the continual subsiding of the Water, these Rings dilated slowly and overspread the whole Bubble, descending in order to the bottom of it, where they vanish'd successively. In the mean while, after all the Colours were emerged at the top, there grew in the center of the Rings a small round black Spot, like that in the first Observation, which continually dilated it self till it became sometimes more than 1/2 or 3/4 of an Inch in breadth before the Bubble broke. At first I thought there had been no Light reflected from the Water in that place, but observing it more curiously, I saw within it several smaller round Spots, which appeared much blacker and darker than the rest, whereby I knew that there was some Reflexion at the other places which were not so dark as those Spots. And by farther Tryal I found that I could see the Images of some things (as of a Candle or the Sun) very faintly reflected, not only from the great black Spot, but also from the little darker Spots which were within it.
Besides the aforesaid colour'd Rings there would often appear small Spots of Colours, ascending and descending up and down the sides of the Bubble, by reason of some Inequalities in the subsiding of the Water. And sometimes small black Spots generated at the sides would ascend up to the larger black Spot at the top of the Bubble, and unite with it.
Obs. 18. Because the Colours of these Bubbles were more extended and lively than those of the Air thinn'd between two Glasses, and so more easy to be distinguish'd, I shall here give you a farther description of their order, as they were observ'd in viewing them by Reflexion of the Skies when of a white Colour, whilst a black substance was placed behind the Bubble. And they were these, red, blue; red, blue; red, blue; red, green; red, yellow, green, blue, purple; red, yellow, green, blue, violet; red, yellow, white, blue, black.
The three first Successions of red and blue were very dilute and dirty, especially the first, where the red seem'd in a manner to be white. Among these there was scarce any other Colour sensible besides red and blue, only the blues (and principally the second blue) inclined a little to green.
The fourth red was also dilute and dirty, but not so much as the former three; after that succeeded little or no yellow, but a copious green, which at first inclined a little to yellow, and then became a pretty brisk and good willow green, and afterwards changed to a bluish Colour; but there succeeded neither blue nor violet.
The fifth red at first inclined very much to purple, and afterwards became more bright and brisk, but yet not very pure. This was succeeded with a very bright and intense yellow, which was but little in quantity, and soon chang'd to green: But that green was copious and something more pure, deep and lively, than the former green. After that follow'd an excellent blue of a bright Sky-colour, and then a purple, which was less in quantity than the blue, and much inclined to red.
The sixth red was at first of a very fair and lively scarlet, and soon after of a brighter Colour, being very pure and brisk, and the best of all the reds. Then after a lively orange follow'd an intense bright and copious yellow, which was also the best of all the yellows, and this changed first to a greenish yellow, and then to a greenish blue; but the green between the yellow and the blue, was very little and dilute, seeming rather a greenish white than a green. The blue which succeeded became very good, and of a very bright Sky-colour, but yet something inferior to the former blue; and the violet was intense and deep with little or no redness in it. And less in quantity than the blue.
In the last red appeared a tincture of scarlet next to violet, which soon changed to a brighter Colour, inclining to an orange; and the yellow which follow'd was at first pretty good and lively, but afterwards it grew more dilute until by degrees it ended in perfect whiteness. And this whiteness, if the Water was very tenacious and well-temper'd, would slowly spread and dilate it self over the greater part of the Bubble; continually growing paler at the top, where at length it would crack in many places, and those cracks, as they dilated, would appear of a pretty good, but yet obscure and dark Sky-colour; the white between the blue Spots diminishing, until it resembled the Threds of an irregular Net-work, and soon after vanish'd, and left all the upper part of the Bubble of the said dark blue Colour. And this Colour, after the aforesaid manner, dilated it self downwards, until sometimes it hath overspread the whole Bubble. In the mean while at the top, which was of a darker blue than the bottom, and appear'd also full of many round blue Spots, something darker than the rest, there would emerge one or more very black Spots, and within those, other Spots of an intenser blackness, which I mention'd in the former Observation; and these continually dilated themselves until the Bubble broke.
If the Water was not very tenacious, the black Spots would break forth in the white, without any sensible intervention of the blue. And sometimes they would break forth within the precedent yellow, or red, or perhaps within the blue of the second order, before the intermediate Colours had time to display themselves.
By this description you may perceive how great an affinity these Colours have with those of Air described in the fourth Observation, although set down in a contrary order, by reason that they begin to appear when the Bubble is thickest, and are most conveniently reckon'd from the lowest and thickest part of the Bubble upwards.