At times when much dust is present in the atmosphere, the sky is a milky white color by day as a result of the reflection of sunlight from the dust particles. Sunrise and sunset colors are then particularly gorgeous, with reds predominating. At such times the blue and violet rays are almost completely shut out, and the red, orange and yellow rays are powerfully diffracted and scattered by the dust particles in the air.
The twilight glow that is visible for some time before sunrise or after sunset is, of course, entirely an atmospheric effect caused by the reflection of sunlight to our eyes from the upper atmosphere, upon which the sun shines, while it is, itself, concealed from our view below the horizon. The atmosphere extends in quantities sufficient to produce twilight to an elevation of about sixty miles.
When all the rays of which sunlight is composed are reflected in equal proportions we get the impression of white light. Dust and haze in the air reflect all rays strongly and give a whitish color to an otherwise blue sky. Brilliant white clouds appear white, because they are reflecting all rays equally. Clouds or portions of clouds appear black when they are in shade or, at times, by contrast with portions that are more strongly illuminated, or when they are moisture-laden and near the point of saturation, when they are absorbing more light than they reflect. At sunrise and sunset, when the light that falls upon the clouds is richest in red and orange and yellow, clouds reflect these colors to our eyes, and we see the brilliant sunset hues which are more intense the more the air is filled with dust and impurities.
The familiar and beautiful phenomenon of the rainbow is produced by refraction, reflection and interference of sunlight by drops of falling water, such as rain or spray. As the ray of sunlight enters the drop of water, which acts as a tiny glass prism, it is refracted or bent from its course and spread out into its spectral colors. Reflection of these rays next takes place (once or twice, as the case may be) from the inside of the drop and a second refraction of the reflected ray takes place as it leaves the drop. The smaller the drops the more brilliant is the rainbow and the richer in color. The most brilliant rainbows are produced by drops between 0.2 and 0.4 millimeters in diameter. In addition to the primary bow, which has a red outer border with a radius of 42°, there is the secondary bow with a radius of about 51° and with colors reversed, the red being on the inner border; the supernumerary bows which are narrow bands of red, or green and red, appear parallel to the primary and secondary bows along the inner side of the primary bow and the outer side of the secondary bow. No rainbow arches ever appear between the primary and secondary bows, and it can be shown in fact, that the illumination between these two bows is at a minimum.
The primary, secondary and supernumerary bows all lie opposite the sun in the direction of the observer's shadow and the observer must stand with his back to the sun in order to see them. The primary and secondary rainbow arches take the form of arcs of circles that have their common center on the line connecting the sun with the observer at a point as far below the horizon in angular distance as the sun is above the horizon. It is, therefore, never possible to see a rainbow arch of more than a semicircle in extent unless the observer is at an elevation above the surrounding country, under which circumstances it might be possible to see a complete circle formed by the rainbow.
The highest and longest arch appears when the sun is on the horizon, and the greater the altitude of the sun the smaller and lower the visible arch. As the angular radius of the primary bow is 42° and of the secondary bow 51° and as the common center of the two circles is always as far below the horizon as the sun is above, it is never possible to see either primary or secondary rainbow when the altitude of the sun is over 51°, or the primary bow when the altitude is over 42°. For this reason rainbows are rarely seen at or near noon in mid-latitudes, since the sun is usually at an elevation of more than 42° at noon, especially in the summer season, which is also the most favorable season for rainbows, owing to the great likelihood of rain and sunshine occurring at the same time.
The light which comes to an observer from the primary bow is once reflected within the drop, and that which comes from the secondary bow is twice reflected within the drop. The sharper and brighter light therefore comes from the primary bow of 42° radius. The space between the two bows is particularly dark, because it can be shown that the drops there do not reflect any light at all.
The rainbow colors are rarely pure or arranged in spectral order, owing to interference of light waves. It is the interference of light waves from different parts of the same drop that produces the bands of alternate maximum and minimum brightness, that lie below the primary bow and beyond the secondary bow. The red or green and red bands of maximum brightness produced thus by interference, are called the supernumerary bows, and they are always found parallel to the primary and secondary bow within the former and above the latter.
The distance of the rainbow from the observer is the distance of the drops that form it. A rainbow may be formed by clouds several miles distant or by the aid of the garden hose on our lawn. No two observers can see exactly the same rainbow because the rainbow arch encircles the surface of a cone whose vertex is at the observer's eye and no two such vertices can exactly coincide. Two observers see rainbows formed by different drops.