Many of the rich silver-mines of the Pacific mountains occur in fissures and cavities in sedimentary rocks, mainly limestone. Instances of this nature are furnished by certain mines in northeastern Mexico, where the ore is found in cavities in Cretaceous limestone; at Leadville and Aspen, Colorado; Big and Little Cottonwood cañons, and the Horn silver-mine, Utah, where the principal country rock is Carboniferous limestone; the Eureka district, Nevada, where the ore occurs in cavities in Cambrian limestone. In the case of several of these mines, igneous rock is near at hand, and the ores are believed to owe their concentration largely to the action of heated waters.
In other regions deep fissures, occupied in part by dikes of igneous rock, have permitted of the ascent of water charged with mineral matter from far below the surface; such waters are heated, in part by the general heat of the earth's interior, or, if in association with dikes, by the heat of the once molten intruded rock. The ascending hot water is an active solvent, and as it rises
becomes cooled, and for this and other reasons precipitates many mineral substances. Veins are thus formed, which are many times banded—that is, result from the filling of fissures by the successive deposition of minerals of various kinds on their walls, each different layer of minerals indicating a change in conditions. Fissures filled in this manner from below, as denudation progresses, become exposed at the surface and reconcentration through the influence of disintegration and decay, and of solution and redeposition by descending water takes place. Ore bodies of this character carrying gold, silver, mercury, etc., are of wide occurrence, especially in the Pacific mountains, but the process of concentration is independent of the nature of the country rock. Segregated and fissure veins occur in either igneous, sedimentary, or metamorphic terranes, but are more commonly of economic importance in the metamorphic rocks than elsewhere, and will be referred to again in that connection.
Economic Importance of the Metamorphic Terranes.—The great laboratory in which rocks undergo important changes in their physical condition and in mineralogical and chemical composition, is what has been termed on a previous page the zone of metamorphism. The depth of the upper limit of this zone is variable, dependent in part on the nature of the rocks and on movements within them, as is the case of mountain building. In fact, there is probably no well-defined limit to the zone either above or below, as in the former direction metamorphism merges by gradations into alteration produced by the descent of surface water, and in the latter direction as heat increases passes again, as we imagine, by insensible and irregular gradations into a region where the rocks are so highly heated that diffusion rather than concentration results. Whether the rocks below the zone of metamorphism are fused or not depends on pressure. They are probably solid, but in a potentially plastic condition, and become fused and may be forced upward through fissures in the condition of igneous magmas when pressure is relieved. The zone of metamorphism lies between a superior zone where
alteration by descending water is dominant, and a lower region where alteration due mainly to heat is in control. In the zone of metamorphism the influence of heated percolating waters, combined with movements in the rocks, are the principal factors which lead to the concentration of mineral substances.
Under the influence of percolating, heated waters, new minerals are formed in sedimentary or igneous rocks, and rocks once metamorphosed may undergo additional changes. Mineral matter previously widely disseminated through rocks is, under the action of percolating, heated water, brought together and the regeneration and crystallization of a large variety of ores and minerals result. The birthplace of a large variety of ores and minerals is in the zone of metamorphism. It is in metamorphic rocks that the geologist looks for gems, the precious metals, crystalline marble, magnetic iron, etc.
For the most part, however, the native metals and ores of the precious and many of the common metals are too widely disseminated in the metamorphic rocks to be of commercial importance, and a still further concentration, principally in fissures and other cavities, is necessary before they can be of value to man. This secondary concentration is much the same as in the case of the deposition of lead and zinc ores in cavities in sedimentary rocks, and results largely from the solution and redeposition, sometimes by replacement, of mineral matter by heated waters.
Certain ores and rocks contained in metamorphic terranes owe their concentration to previously acting processes of concentration, but have undergone chemical changes in place. Illustrations of this class of ores, etc., are furnished by the magnetite and hematite contained in the metamorphic rocks on the eastern border of the Appalachians, in New England, eastern Canada, and the Lake Superior region. These ore bodies, frequently of great size, in some instances furnish evidence of having been originally lenticular masses of bog-iron ore, or ferric carbonate, associated with sedimentary beds, and originally
concentrated, as already mentioned, at the surface through the action of water charged with carbon dioxide, but principally on account of the influence of heat have been changed to a higher degree of oxidation and now appear as hematite, as, for example, in the iron districts of the northern portions of Michigan, Minnesota, Wisconsin, and the Ozark Hills, or still further altered as in the richest of all iron ores, magnetite, so abundant in the metamorphic rocks of the Appalachian region, about the Adirondack hills, widely and in extensive bodies in eastern Canada, about the south shore of Lake Superior, in Texas, etc.
In certain instances, as has been shown by C. R. Van Hise and others, hematite ore, like that of the Lake Superior region, has resulted from the alteration of ferrous carbonate which had replaced limestone by a chemical process of solution and double decomposition.