And know it will be gold another day.”
Is there “any new thing under the sun?”
With regard to auriferous pyritous lodes, it does not appear even now to be clear, as some scientists assert, that their gold is never found in chemical combination with the sulphides of the base metals. On the contrary, I think much of the evidence points in the other direction.
I have long been of opinion that it is really so held in many of the ferro-sulphides and arsenio-ferro sulphides. On this subject Mr. T. Atherton contributed a short article in 1891 to the Australian Mining Standard which is worthy of notice. He says, referring to an occurrence of a Natural Sulphide of Gold:—“The existence of gold, in the form of a natural sulphide in conjunction with pyrites, has often been advanced theoretically, as a possible occurrence; but up to the present time has, I believe, never been established as an actual fact.” During my investigations on the ore of the Deep Creek mines, Nambucca, New South Wales, I found in them what I believe to be gold existing as a natural sulphide. The lode is a large irregular one of pure arsenical pyrites carrying, in addition to gold and silver, nickel and cobalt. It exists in a felsite dyke immediately on the coast. Surrounding it on all sides are micaceous schists, and in the neighbourhood about half a mile distant is a large granite hill about 800 feet high. In the lode and its walls are large quantities of pyrophyllite, and in some parts of the mine there are deposits of pure white translucent mica, but in the ore itself it is a yellow or pale olive green, and is never absent from the pyrites.
From the first I was much struck with the exceedingly fine state of division in which the gold existed in the ore. After roasting and very carefully grinding down in an agate mortar, I have never been able to get any pieces of gold exceeding one-thousandth of an inch in diameter, and the greater quantity is very much finer than this. Careful dissolving of the pyrites and gangue so as to leave the gold intact failed to find it in any larger diameter. As this was a very unusual experience in investigations on many other kinds of pyrites, I was led further into the matter.
Ultimately, after a number of experiments, there was nothing left but to test for gold existing as a natural sulphide. Taking 200 gr. of gold from a sample assaying 17 oz. fine gold per ton, grinding it finely and heating for some hours with yellow sodium sulphide—on decomposing the filtrate and treating for gold I got a result at the rate of 12 oz. per ton. This was repeated several times with the same result.
This sample came from the lode at the 140 ft. level, whilst samples from the higher levels where the ore is more oxidised, although carrying the gold in exactly the same degree of fineness, do not give as high a percentage of auric sulphide.
It would appear that all the gold in the pyrites (and I have never found any gold existing apart from the pyrites) has originally taken its place there as a sulphide.
The following is an analysis of a general sample insoluble in nitro-sulphuric acid:—