A basin with nitrate of mercury may be kept handy, and the plates touched up from time to time for a few days until they get amalgamated with gold, after which, unless you have much base metal to contend with, they will give no further trouble.
It must be remembered, however, that an excessive use of nitric acid will result in waste of mercury, which will be carried off in a milky stream with the water; and also that it will cause the amalgam to become very hard, and less active in attracting other particles of gold.
If you are treating the plate with nitrate of silver prepared as already mentioned, clean the plate with dilute nitric acid, rub the surface with the ball of amalgam, following with the swab and fairly rubbing in. It will be well to prepare the plate some days before requiring to use it, as a better adhesion of the silver and copper takes place than if mercury is applied at once.
To amalgamate with zinc amalgam, clean the copper plate by means of a swab, with fairly strong sulphuric acid diluted with water; then while wet apply the zinco-mercury amalgam and well rub in. To prepare the zinc amalgam, clip some zinc (the lining of packing cases will do) into small pieces and immerse them in mercury after washing them with a little weak sulphuric acid and water to remove any coating of oxide. When the mercury will absorb no more zinc, squeeze through chamois leather or calico (as for silver amalgam), and well rub in. The plate thus prepared should stand for a few days, dry, before using. If, before amalgamation with gold takes place, oxide of copper or other scum should rise on this plate a little very dilute sulphuric acid will instantly remove it.
Sodium and cyanide of potassium are frequently used in dressing-plates, but the former should be very sparingly employed, as it will often do more harm than good by taking up all sorts of base metals with the amalgam, and so presenting a surface which the gold will pass over without adhering to. Where water is scarce, and is consequently used over and over again, lime may be added to the pulp, or, if lime is not procurable, wood ashes may be used. The effect is two-fold; the lime not only tends to “sweeten” sulphide ores and keep the tables clean, but also causes the water to cleanse itself more quickly of the slimes, which will be more rapidly precipitated. When zinc amalgam is used, alkalies would, of course, be detrimental.
When no other water than that from the mine is available, difficulties often arise owing to the impurities it contains. These are various, but among the most common are the soluble sulphates, and sometimes free sulphuric acid evolved by the oxidisation of metallic sulphides. In the presence of this difficulty, do one of two things: either utilise or neutralise. In certain cases, I recommend the former. Some time since I was treating, for gold extraction, material from a mine which was very complex in character. For this ore I coined the term “polysynthetic.” This contained about half a dozen different sulphides. The upper parts of the lode being partially oxidised, free sulphuric acid (H₂SO₄) was evolved. I therefore, following out a former discovery, added a little metallic zinc to the mercury in the boxes and on the plates with excellent results. When the free acid in the ore began to give out in the lower levels I added minute quantities of sulphuric acid to the water from time to time. I have since found, however, that with some water, particularly West Australian, the reaction is so feeble (probably owing to the lime and magnesia present) as to make this mode of treatment unsuitable.
HOW TO MAKE A DOLLY.
Fig. 35. Dolly.