Among the theories which they discredit is that ore bodies may usually be assumed to become richer in depth. As applied to gold lodes the teaching of experience does not bear out this view.
If it be taken into account that the time in which most of our auriferous siliceous lodes were formed was probably that indicated in Genesis as before the first day or period when "the earth was without form and void, and darkness was upon the face of the deep," it will be realised that the action we behold now taking place in a small way in volcanic regions, was probably then almost universal. The crust of the earth had cooled sufficiently to permit water to lie on its surface, probably in hot shallow seas, like the late Lake Rotomahana. Plutonic action would be very general, and volcanic mud, ash, and sand would be ejected and spread far and wide, which, sinking to the bottom of the water, may possibly be the origin of what we now designate the azoic or metamorphic slates and schists, as also the early Cambrian and Silurian strata. These, from the superincumbent weight and internal heat, became compacted, and, in some cases, crystallised, while at the same time, from the ingress of the surface waters to the heated regions below, probably millions of geysers were spouting their mineral impregnated waters in all directions; and in places where the crust was thin, explosions of super-heated steam caused huge upheavals, rifts, and chasms, into which these waters returned, to be again ejected, or to be the cause of further explosions. Later, as the cooling-process continued, there would be shrinkages of the earth's crust causing other fissures; intrusive granites further dislocated and upheaved the slates. About this age, probably, when really dry land began to appear, came the first formation of mineral lodes, and the waters, heavily charged with silicates, carbonates of lime, sulphides, etc., in solution, commenced to deposit their contents in solid form when the heat and pressure were removed.
I am aware that part of the theory here propounded as to the probable mode of formation of the immense sedimentary beds of the Archaic or Azoic period is not altogether orthodox—i.e., that the origin of these beds is largely due to the ejection of mud, sand, and ashes from subterraneous sources, which, settling in shallow seas, were afterwards altered to their present form. It is difficult, however, to believe that at this very early period of geologic history so vast a time had elapsed as would be required to account for these enormous depositions of sediment, if they were the result only of the degradation of previously elevated portions of the earth's surface by water agency. Glacial action at that time would be out of the question.
But what about the metals? Whence came the metallic gold of our reefs and drifts? What was it originally—a metal or a metallic salt, and if the latter, what was its nature?—chloride, sulphide, or silicate, one, or all three? I incline to the latter hypothesis. All three are known, and the chemical conditions of the period were favorable for their natural production. Assuming that they did exist, the task of accounting for the mode of occurrence of our auriferous quartz lodes is comparatively simple. Chloride of gold is at present day contained in sea water and in some mineral waters, and would have been likely to be more abundant during the Azoic and early Paleozoic period.
Sulphide of gold would have been produced by the action of sulphuretted hydrogen; hence probably our auriferous pyrites lodes, while silicate of gold might have resulted from a combination of gold chlorides with silicic acid, and thus the frequent presence of gold in quartz is accounted for.
A highly interesting and instructive experiment, showing how gold might be, and probably was, deposited in quartz veins, was carried out by Professor Bischof some years ago. He, having prepared a solution of chloride of gold, added thereto a solution of silicate of potash, whereupon, as he states, the yellow colour of the chloride disappeared, and in half an hour the fluid turned blue, and a gelatinous dark-blue precipitate appeared and adhered to the sides of the vessel. In a few days moss-like forms were seen on the surface of the precipitate, presumably approximating to what we know as dendroidal gold—that is, having the appearance of moss, fern, or twigs. After allowing the precipitate to remain undisturbed under water for a month or two a decomposition took place, and in the silicate of gold specks of metallic gold appeared. From this, the Professor argues, and with good show of reason, that as we know now that the origin of our quartz lodes was the silicates contained in certain rocks, it is probable that a natural silicate of gold may be combined with these silicates. If this can be demonstrated, the reason for the almost universal occurrence of gold in quartz is made clear.
About 1870, Mr. Skey, analyst to the New Zealand Geological Survey Department, made a number of experiments of importance in respect to the occurrence of gold. These experiments were summarised by Sir James Hector in an address to the Wellington Philosophical Society in 1872. Mr. Skey's experiments disproved the view generally held that gold is unaffected by sulphur or sulphuretted hydrogen gas, and showed that these elements combined with avidity, and that the gold thus treated resisted amalgamation with mercury. Mr. Skey proved the act of absorption of sulphur by gold to be a chemical act, and that electricity was generated in sufficient quantity and intensity during the process to decompose metallic solutions. Sulphur in certain forms had long been known to exercise a prejudicial effect upon the amalgamation of gold, but this had always been attributed to the combination of the sulphur with the quicksilver used. Now, however, it is certain that the sulphurising of the gold must be taken into account. We must remember that the particles of gold in the stone may be enveloped with a film of auriferous sulphide, by which they are protected from the solvent actions of the mercury. The sulphurisation of the gold gives no ocular manifestation by change of colour or perceptible increase of weight, as in the case of the formation of sulphides of silver, lead and other metals, on account of the extremely superficial action of the sulphur, and hence probably the existence of the gold sulphide escaped detection by chemists.
Closely allied to this subject is the investigation of the mode in which certain metals are reduced from their solutions by metallic sulphides, or, in common language, the influence which the presence of such substances as mundic and galena may exercise in effecting the deposit of pure metals, such as gold, in mineral lodes. The close relation which the richness of gold veins bears to the prevalence of pyrites has been long familiar both to scientific observers and to practical miners. The gold is an after deposit to the pyrites, and, as Mr. Skey was the first to explain, due to its direct reducing influences. By a series of experiments Mr. Skey proved that the reduction of the metal was due to the direct action of the sulphide, and showed that each grain of iron pyrites, when thoroughly oxidised, will reduce 12 1/4 grains of gold from its solution as chloride. He also included salts of platina and silver in this general law, and demonstrated that solutions of any of these metals traversing a vein rock containing certain sulphides would be decomposed, and the pure metal deposited. We are thus enabled to comprehend the constant association of gold, or native alloys of gold and silver, in veins which traverse rocks containing an abundance of pyrites, whether they have been formed as the result of either sub-aqueous volcanic outburst or by the metamorphism of the deeper-seated strata which compose the superficial crust of the earth.
Mr. Skey also showed by very carefully conducted experiments that the metallic sulphides are not only better conductors of electricity than has hitherto been supposed, but that when paired they were capable of exhibiting strong electro-motive power. Thus, if galena and zinc blende in acid solutions be connected in the usual manner by a voltaic pair, sulphuretted hydrogen is evolved from the surface of the former, and a current generated which is sufficient to reduce gold, silver or copper from their solutions in coherent electro-plate films. The attributing of this property of generating voltaic currents, hitherto supposed to be almost peculiar to metals, to such sulphides as are commonly found in metalliferous veins, further led Mr. Skey to speculate how far the currents discovered to exist in such veins by Mr. E. F. Fox might be produced by the gradual oxidation of mixed sulphides, and that veins containing bands of different metallic sulphides, bounded by continuing walls, and saturated with mineral waters, may constitute under some circumstances a large voltaic battery competent to produce electro-deposition of metals, and that the order of the deposit of these mineral lodes will be found to bear a definite relation to the order in which the sulphides rank in the table of their electro-motive power. These researches may lead to some clearer comprehension of the law which regulates the distribution of auriferous veins, and may explain why in some cases the metal should be nearly pure, while in others it is so largely alloyed with silver.
The following extract was lately clipped from a mining paper. If true, the experiment is interesting:—