I have long been of opinion that it is really so held in many of the ferro-sulphides and arsenio-ferro sulphides. On this subject Mr. T. Atherton contributed a short article in 1891 to the Australian Mining Standard which is worthy of notice. He says, referring to an occurrence of a Natural Sulphide of Gold: "The existence of gold, in the form of a natural sulphide in conjunction with pyrites, has often been advanced theoretically, as a possible occurrence; but up to the present time has, I believe, never been established as an actual fact. During my investigation on the ore of the Deep Creek mines, Nambucca, New South Wales, I have found in them what I believe to be gold existing as a natural sulphide. The lode is a large irregular one of pure arsenical pyrites carrying, in addition to gold and silver, nickel and cobalt. It exists in a felsite dyke immediately on the coast. Surrounding it on all sides are micaceous schists, and in the neighbourhood about half a mile distant is a large granite hill about 800 feet high. In the lode and its walls are large quantities of pyro-phyllite, and in some parts of the mine there are deposits of pure white translucent mica, but in the ore itself it is a yellow or pale olive green, and is never absent from the pyrites.
"From the first I was much struck with the exceedingly fine state of division in which the gold existed in the ore. After roasting and very carefully grinding down in an agate mortar, I have never been able to get any pieces of gold exceeding one-thousandth of an inch in diameter, and the greater quantity is very much finer than this. Careful dissolving of the pyrites and gangue so as to leave the gold intact failed to find it in any larger diameter. As this was a very unusual experience in investigations on many other kinds of pyrites, I was led further into the matter.
"Ultimately, after a number of experiments, there was nothing left but to test for gold existing as a natural sulphide. Taking 200 gr. of ore from a sample assaying 17 oz. fine gold per ton, grinding it finely and heating for some hours with yellow sodium sulphide—on decomposing the filtrate and treating for gold I got a result at the rate of 12 oz. per ton. This was repeated several times with the same result.
"This sample came from the lode at the 140 ft. level, whilst samples from the higher levels where the ore is more oxidised, although carrying the gold in exactly the same degree of fineness, do not give as high a percentage of auric sulphide.
"It would appear that all the gold in the pyrites (and I have never found any gold existing apart from the pyrites) has originally taken its place there as a sulphide."
Professor Newbery, who made many valuable suggestions on the subject, says, speaking of gold in pyritous lodes:
"As it (the gold salt) may have been in the same solution that deposited the pyrites, which probably contained its iron in the form of proto-carbonate with sulphates, it was not easy at first to imagine any ordinary salt of gold; but this I find can be accomplished with very dilute solutions in the presence of an alkaline carbonate and a large excess of carbonic acid, both of which are common constituents of mineral waters, especially in Victoria. This is true of chloride of gold, and if the sulphide is required in solution, it is only necessary to charge the solution with an excess of sulphuretted hydrogen. In this matter both sulphides may be retained in the same solution, depositing gradually with the escape of the carbonic acid."
Pyritic lodes usually contain a considerable proportion of calcareous matter, mostly carbonates, and consequently it appears not improbable that the gold may remain in some instances as a sulphide, particularly in samples of pyrites, in which it cannot be detected even by the microscope until by calcination the iron sulphide is changed to an oxide, wherein the gold may be seen in minute metallic specks. The whole subject is full of interest, and careful scientific investigation may lead to astonishing results.