A very remarkable nugget weighing 16 3/4 oz. was sluiced from near the surface in one of my own mining properties at Woodside, South Australia, some years ago, which illustrated the nuclear theory very beautifully. This nugget is very irregular in shape, fretted and chased as though with a jeweller's graving tool, showing plainly the shape of the pyritous crystals on which it was formed while the interstices were filled with red hematite iron just as found in artificially formed nuggets on a sulphide of iron base. The author has a nugget from the same locality weighing about 1 1/2 oz. which exhibits in a marked degree the same characteristics, as indeed does most of the alluvial gold found in the Mount Lofty Ranges; also a nugget from near the centre of Australia weighing four ounces, in which the original crystals of pyrites are reproduced in gold just as an iron horse-shoe, placed in a launder through which cupriferously impregnated water flows, will in time be changed to nearly pure copper and yet retain its shape.
Now with regard to the four points I have put as to the apparent anomalies of occurrence of alluvial gold. The reason why alluvial gold is of finer quality as a rule than reef is probably because while gold and silver, which have a considerable affinity for each other, were presumably dissolved from their salts and held in solution in the same mineral water, they would in many cases not be deposited together, for the reason that silver is most readily deposited in the presence of alkalies, which would be found in excess in mineral waters coming direct from the basic rocks, while gold is induced to precipitate more quickly in acid solutions, which would be the character of the waters after they had been exposed to atmospheric action and to contact with organic matters.
This, then, may explain not only the comparatively greater purity of the alluvial gold, but also why big nuggets are found so far from auriferous reefs, and also why heavy masses of gold have been frequently unearthed from among the roots even of living trees, but more particularly in drifts containing organic matter, such as ancient timber.
All, then, that has been adduced goes to establish the belief that the birthplace of our gold is in certain of the earlier rocks comprising the earth's crust, and that its appearance as the metal we value so highly is the result of electro-chemical action, such as we can demonstrate in the laboratory.
CHAPTER VI
GOLD EXTRACTION
We now come to a highly important part of our subject, the practical treatment of ores and matrixes for the extraction of the metals contained. The methods employed are multitudinous, but may be divided into four classes, namely, washing, amalgamating with mercury, chlorinating, cyaniding and other leaching processes, and smelting. The first is used in alluvial gold and tin workings and in preparing some silver, copper, and other ores for smelting, and consists merely in separating the heavier metals and minerals from their gangues by their greater specific gravity in water. The second includes the trituration of the gangue and the extraction of its gold or silver by means of mercury. Chlorinating and leaching generally is a process whereby metals are first changed by chemical action into their mineral salts, as chloride of gold, nitrate of silver, sulphate of copper, and being dissolved in water are afterwards redeposited in the metallic form by means of well-known re-agents.
In really successful mining it is in the last degree important that the mode of extraction of metals in the most scientific manner should be thoroughly understood, but as a general rule the science of metallurgy is but very superficially grasped even by those whose special business it is to treat ore bodies in order to extract their metalliferous contents, and whether in quartz crushing mill, lixiviating, or smelting works there is much left to be desired in the method of treating our ores.
My attention was recently attracted to an article written by Mr. F. A. H. Rauft, M.E., from which I make the following extract: