Tufa and Travertine
The tufa ([fig. 23]) and travertine occurring as surficial deposits in Illinois were formed by springs. The deposits usually occur at or near the outcrop of a layer of porous water-bearing earth material, such as gravel, sandstone, or fissured limestone, that is underlain by a nonporous clay or shale formation. Water moving down through the porous layer cannot sink through the clay or shale and so is forced to move laterally. Where valleys have cut into the layers of gravel or rock, the water emerges as springs.
If the material through which the water has passed is limestone, or gravel containing limestone as most Illinois gravels do, some of the limestone is likely to have dissolved in the water. When the water issues as a spring, conditions may be such as to cause precipitation of the dissolved limestone as tufa or, more rarely, travertine.
Tufa is generally highly porous and more or less impure, whereas travertine is harder and less porous.
The middle or lower slopes of bluffs are common sites for spring-deposited tufa or travertine. Deposits have been seen in various parts of Illinois, but are not known to have been worked, except in Calhoun County where small quantities of tufa were produced for use as agricultural limestone. It is thought that the tufa and travertine deposits of Illinois are relatively small, but they may be of local importance.
Figure 23—Calcareous tufa from Pike County. In addition to the large visible pores there are numerous tiny ones.
Pyrite and Marcasite
The mineral pyrite consists of iron and sulfur as the compound iron sulfide (FeS₂) and, because of its shiny, brassy yellow color, is sometimes called fool’s gold. Marcasite has the same composition as pyrite, but its crystals have a different shape and it is often lighter colored. Both minerals occur in various parts of the state; they are particularly prevalent in some coal seams, and when so occurring are in some cases called coal brasses or “sulfur.”
Pyrite and marcasite are used commercially as raw materials for making sulfuric acid, although sulfur itself is more extensively used for that purpose. At one time coal brasses recovered during coal-cleaning operations at a northwestern Illinois coal mine were sold for acid making. A large quantity of coal brasses probably could be recovered from such operations at Illinois coal mines.