We remarked, that, in common sky rockets, the charges consist of a mixture of gunpowder, saltpetre, and charcoal, with occasionally other additions, as steel-filings. Rocket-stars, on the contrary, are usually formed of mealed powder, saltpetre, sulphur, and sometimes other substances according to the colour of the flame required. Thus, for the white star, composition oil of spike, (a preparation of Barbadoes tar, and spirit of turpentine), and camphor are employed; the camphor giving to the flame a white appearance. The blue stars owe their colour to sulphur, which is in the proportion of one to four of the meal-powder; the variegated stars have the same materials, with sulphur vivum, and camphor; and the brilliant stars, common stars, and a variety of others, we shall mention in their proper places, are all formed by the addition of sundry substances.
The variety of rains, as gold rain, silver rain, &c. are differently prepared. Besides saltpetre, meal-powder, and sulphur, gold rain contains in its composition the filings of brass, saw-dust, and pulverized glass. In this instance, the saw-dust communicates colour, while the brass and the glass are thrown out, the former partly consumed, and the latter partially fused by the intense heat. The same effect may be produced by meal-powder, saltpetre, and charcoal, or saltpetre, sulphur, antimony, brass filings, saw-dust, and pulverized glass. Here the antimony, as well as the brass, communicates the golden colour. (See [antimony.]) Silver rain is generally formed of saltpetre, sulphur, meal-powder, antimony, and sal prunelle, but without saw-dust; the antimony communicating silver brilliancy to the flame. It may also be formed, by employing, in given proportions, saltpetre, sulphur, and charcoal, the particular effect depending upon the proportions; or by using antimony in lieu of the charcoal, or in the place of the antimony, steel-filings. Whether antimony or steel-filings are used, the effect of their combustion is the same, forming in the one instance, an oxide of antimony, and in the other, an oxide of iron. Both gold and silver rain is employed chiefly for sky-rockets. As to the colours required, they may be formed of other substances.
The charges for water-rockets are also various. In some of which, besides the usual ingredients, (meal-powder, saltpetre, and sulphur,) sea-coal, steel-filings, saw-dust, &c. enter into their composition.
As to the different compositions, it will be sufficient to remark, that for wheels, fixed cases, sun cases, gerbes, Chinese fire, tourbillons, water balloons, water squibs, serpents, port-fires, cones, globes, air-balloon fuses, fire-pumps, and many others to be noticed hereafter, the basis of them is either gunpowder or saltpetre, and sulphur and charcoal, with or without additions. With respect to the composition of the stars of different colours, it is to be observed, that the particular colour is given by pulverized cast-iron, steel-filings, camphor, amber, antimony, perchloride of mercury, (corrosive sublimate), ivory-dust, copper, frankincense, &c. To produce tails of sparks, pitch or rosin is added. Stars which produce some sparks are usually made by using gum water in mixing the composition. The gum appears to produce a separation of the inflammable substances, and, as it is not combustible, to check, as it were, the rapidity of the combustion. In some preparations, also, isinglass or fish-glue is used in solution. This, no doubt, acts in the same manner, as well as to give firmness to the composition; but its solution is also used as a vehicle. On the same principle also, we learn the use of caustic ley, quicklime, &c. in preparing match-rope. After soaking the cord in a solution of nitre, it is afterwards dipped into ley, which is nothing more than a solution of potash rendered caustic by means of quicklime. The potash evidently checks the combustion. The formulæ for slow match, are, however, various. In the match-wood, also, prepared from the wood or bark of the linden, the wood is usually first soaked in a solution of saltpetre, and afterwards in a solution of acetate or sugar of lead, &c. For the same purpose, nitrate of copper is recommended. For stars of a yellow colour, besides gum arabic, or gum tragacanth, saltpetre, and sulphur, the addition of powdered glass, orpiment, (sulphuret of arsenic), and white amber, are occasionally made. The colour is owing to the amber and the orpiment, which have the property of communicating it to flame. We may observe, generally, that the colours produced by different compositions, is a subject of importance to the pyrotechnist. He should know the properties of each substance, and the effect of each ingredient; and, with respect to their action, be able to foretell the appearance of the flame, and other circumstances connected with the art. As a general example, we may state, that sulphur gives a blue; camphor, a white, or pale colour; saltpetre, a clear white yellow; amber, a colour inclining to yellow; muriate of ammonia, (sal ammoniac), a green; antimony, a reddish; rosin, a copper colour, and Greek pitch, a bronze, or a colour between red and yellow. In using these substances, the following remarks may be useful;—that for producing a white flame, the saltpetre should be the chief part; for blue, the sulphur; for flame inclining to red, the saltpetre should be the principal ingredient, using at the same time, antimony and pitch. (See [matches of different colours], in Part ii.)
Coloured flame may be produced by various other substances, many of which are expensive, and therefore could not be employed economically. Thus, in fire-works made with hydrogen gas, or inflammable air, which have a pleasing effect, by forcing the gas, either from a bladder, oiled-silk bag, or gas-holder, through a variety of revolving jets, which are so arranged as to exhibit stars, or through pipes furnished with small apertures, &c. to resemble different standing figures,—the effect may be varied by previously mixing the gas with the vapour of ether, and other substances, which communicate to the flame, particular colours, which, in a darkened room, are extremely brilliant. Cartwright's fire-works are formed in this manner. (See [fire-works with inflammable air].)
Muriate of strontian, mixed with alcohol, or spirit of wine, will give a carmine-red flame. For this experiment, one part of the muriate is added to three or four parts of alcohol. Muriate of lime produces, with alcohol, an orange-coloured flame. Nitrate of copper produces an emerald-green flame. Common salt and nitre, with alcohol, give a yellow flame. (See [Illuminations and Transparencies].)
In addition to the facts already stated, it may be proper to observe, that the ingredients employed to show in sparks, which are rammed in choaked cases, are various, according to the colours required; as black, white, gray, and red. The black charges are composed of meal-powder and charcoal; the white, of saltpetre, sulphur, and charcoal; the gray, of meal powder, saltpetre, sulphur, and charcoal; and the red, of meal-powder, charcoal, and saw-dust. These are considered regular or set charges, to which we may add two others, called compound and brilliant charges. The compound charges contain a variety of substances which afford sparks; and hence, besides the usual inflammable bodies, saw-dust, antimony, steel and brass-filings, are used. The brilliant fires owe their particular effect to the presence of steel-filings, or pulverized cast-iron. Iron, in any of its states, when minutely divided, has the same effect.
Quick match is usually formed of cotton, by soaking it in a solution of nitre, and adding meal-powder. A solution of isinglass is sometimes used. The etoupille of the French is of the same nature. The manner, quick and slow match, &c. are prepared, with the various formulæ, will be considered under their respective heads. Touch paper, for capping serpents, crackers, &c. will also be noticed. The pyrotechnical spunge owes its inflammability to nitre.
In the various composition of aquatic fire-works, although more care and attention are required, it is to be observed, that, in forming water-rockets, horizontal wheels, water-mines, fire-globes, water-balloons, water-squibs, water-fire-fountains, and the like, substances are generally used along with the usual ingredients, which, under particular circumstances, may be said to repel, as well as resist the action of the water; and in this particular they resemble the celebrated Greek fire, of which we shall speak hereafter. This remark, however, applies only to certain works. After the rockets have been filled, their ends are dipped in melted rosin or sealing-wax, or secured with grease.
Fire-works, usually exhibited in rooms, are made with odoriferous gums and perfumes, and hence are called odoriferous fire-works. We may remark, that the odour or perfume is given by a variety of substances; for these, at a high temperature, are partly consumed, and partly evaporated. Thus camphor, yellow amber, flowers of benzoin, myrrh, frankincense, cedar-raspings, and the essential oils, particularly of bergamot, are employed for this purpose. Scented fire-works are of the same character. The Italians and the French, who have made more experiments in Pyrotechny, than other nations, have improved odoriferous fire-works. In these compositions, they also employ storax, calamite, gum benzoin, and other substances. Scented fire was greatly in use in Egypt, Rome, and Athens, at their fetes and public ceremonies. The unpleasant smell which gunpowder, sulphur, &c. occasion in a confined apartment, has induced the modern artificers to add sundry odoriferous substances to their pyro-mixtures. On this subject, it will be sufficient to observe, that the scented vase, which was in use at Athens, contained the following substances: storax, benzoin, frankincense, camphor, gum juniper in grains, and charcoal of the willow. It does not appear that nitre was employed. The custom of burning frankincense before the altar, is indeed very ancient; for, in the primitive temple at Jerusalem, the custom was adopted by the priests in the Sanctum Sanctorum, and is continued by the Greeks and Armenians, the Jews, the Turks, the Persians, (especially the followers of Zoroaster), preserve this custom. The Holy Fire of the latter is nothing more than the inflamed carburetted hydrogen gas, which comes from the naphtha ground at Baku.