The main classes and divisions of the Library of Congress Classification are as follows:
| A | General Works. Polygraphy |
| AC | Collections. Series. Collected Works |
| AE | Encyclopædias |
| AG | General reference works (other than encyclopædias) |
| AI | Indexes |
| AM | Museums |
| AN | Newspapers |
| AP | Periodicals |
| AS | Societies. Academies |
| AY | Year-books. Almanacs |
| AZ | General history of knowledge and learning |
| B | Philosophy. Religion |
| B-J | Philosophy |
| B | Collections. History. Systems |
| BC | Logic |
| BD | Metaphysics |
| | Introductions to Philosophy. Treatises |
| | Epistemology. Theory of knowledge |
| | Onotology |
| | Cosmology. |
| | Teleology |
| | Philosophy of religion |
| BF | Psychology |
| BH | Esthetics |
| BJ | Ethics |
| BL-BV | Religion. Theology |
| BL | Religions. Mythology. Cults |
| BM | Theology. Generalities |
| BN | Historical (Church history) |
| BQ | Exegetical (Bible, etc.) |
| BS | Systematic (Dogmatics. Apologetics) |
| BV | Practical (Pastoral. Homiletics. Liturgies) |
| C | History—Auxiliary sciences |
| CA | Philosophy of history |
| CB | History of civilization (general and general special only) |
| CC | Antiquities. General |
| CD | Archives. Diplomatics |
| CE | Chronology |
| CJ | Numismatics |
| CN | Epigraphy. Inscriptions |
| CE | Heraldry |
| CS | Genealogy |
| CT | Biography |
| D | History and Topography (except America) |
| D | General history |
| DA | British history |
| | 20-690 England |
| | 700-749 Wales |
| | 750-890 Scotland |
| | 900-995 Ireland |
| DB | Austria-Hungary |
| DC | France |
| DD | Germany |
| DE | Classical antiquity |
| DF | Greece |
| DG | Italy |
| DH-DJ | Netherlands |
| | 1-399 Belgium and Holland |
| | 901-921 Belgium |
| | 901-916 Luxemburg. Holland |
| DK | Russia |
| | 100-400 Russia. General. |
| | 401-438 Poland |
| | 451-470 Finland |
| | 751-999 Russia in Asia |
| DL | Scandinavia |
| | 1-81 Scandinavia. General |
| | 101-296 Denmark |
| | 301-398 Iceland |
| | 401-595 Norway |
| | 601-996 Sweden |
| DP | Spain and Portugal |
| | 1-462 Spain |
| | 500-902 Portugal |
| DQ | Switzerland |
| DR | Turkey and the Balkan States |
| DS | Asia |
| DT | Africa |
| DU | Australia and Oceania |
| E-F | America |
| E | America (general) and United States (general) |
| F | United States (local) and America outside of U.S. |
| G | Geography. Anthropology |
| G | Geography. Voyages. Travel (general) |
| GA | Mathematical and astronomical geography |
| GB | Physical geography |
| GC | Oceanology and oceanography |
| GD | Biography |
| GF | Anthropogeography |
| GN | Anthropology. Somatology. Ethnology. Ethnography, (general). Prehistoric archæology |
| GR | Folk-lore |
| GT | Culture and civilization. Manners and customs |
| GV | Sports and amusements. Games |
| H | Social Sciences. General |
| HA | Statistics |
| HB | Economics, Theory |
| | Economic history. |
| | National production, economic situation (by countries) |
| HD | Economic history. Organization and situation of agriculture and industries |
| | Land. Agriculture |
| | Corporations |
| | Labour |
| | Industries |
| HE | Transportation and communication |
| HF | Commerce, including tariff |
| HG | Finance |
| | Money |
| | Banking |
| | Insurance |
| HJ | Public finance |
| HM | Sociology. General and theoretical |
| HN | Social history. Social reform |
| | Social groups |
| | Family, marriage, women |
| | Associations, secret societies, clubs, etc. |
| | Communities: Urban, Rural |
| | Classes. Aristocracy, third estate, bourgeoisie, peasantry, labouring classes, proletariate, serfs |
| | Nations. Races |
| HV | Social pathology. Philanthropy. Charities and corrections |
| HX | Socialism. Communism. Anarchism |
| J | Political science. Documents |
| | 1-9 Official gazettes |
| | 10-99 United States |
| | 100-999 Other countries. |
| JA | General works |
| JC | Theory of state |
| JF | Constitutional history and administration. General |
| JK | United States |
| JL | Other American States |
| JN | Europe |
| JQ | Asia, Africa, Australia, and Pacific Islands |
| JS | Local Government |
| JV | Colonies and colonization. Emigration and immigration |
| JX | International law |
| K | Law |
| L | Education. General works |
| LA | History of education |
| LB | Theory and practice. Educational psychology. Teaching |
| LC | Special forms, relations, and applications |
| LD | Universities and colleges |
| LE | Other American |
| LF | Europe |
| LG | Asia, Africa, Oceania |
| LH | University, college, and school magazines, etc. |
| LJ | College fraternities and their publications |
| LT | Text-books (general only; special text-books go with their subjects, B-Z) |
| M | Music |
| ML | Musical literature |
| MT | Theory |
| N | Fine Arts. General |
| NA | Architecture |
| NB | Sculpture and related arts |
| NC | Graphic arts in general. Drawing and design |
| ND | Painting |
| NE | Engraving |
| NF | Photography (in art). See TR |
| NK | Art applied to industry. Decoration and ornament |
| P | Language and Literature |
| | Philology and Linguistics |
| PA | Classical philology |
| | 1-199 General |
| | 201-891 Greek languages |
| | 1001-1151 Mediæval and modern |
| | 2001-2899 Latin language |
| PB | Modern European languages. General works |
| | Celtic language |
| | Romance languages |
| | Teutonic languages |
| | General |
| | Gothic |
| | Scandinavian |
| PE | English |
| PF | Frisian |
| | Dutch |
| | German |
| PG | Slavic languages |
| | Lithuanian |
| | Lettish |
| PH | Finnish |
| | Hungarian |
| | Albanian |
| | Basque |
| PJ | Oriental languages. General works |
| | Hamitic |
| | Semitic |
| PK | Indo-Iranian |
| | Armenian |
| | Caucasian |
| PL | Languages of Eastern Asia, Oceania, Africa |
| PM | Hyperborean languages |
| | American languages |
| PN-PV | Literary History. Literature |
| PZ | Fiction |
| Q | Science. General |
| QA | Mathematics |
| | 801-999 Analytic mechanics |
| QB | Astronomy |
| | 281-349 Geodesy |
| QC | Physics |
| | 81-119 Weights and measures |
| | 801-999 Terrestrial magnetism and meteorology |
| QD | Chemistry |
| | 901-999 Crystallography |
| QE | Geology |
| | cf. BG, GC |
| | 351-499 Mineralogy and petrology |
| | 701-999 Palæontology |
| QH | Natural history |
| | 201-299 Microscopy |
| | 301-999 General biology |
| QK | Botany |
| QL | Zoology |
| | 801-999 General anatomy and embryology |
| QM | Human anatomy |
| QP | Physiology |
| QR | Bacteriology |
| R | Medicine. General |
| RA | State medicine. Documents Public health |
| | Medical climatology. Hospitals |
| | Jurisprudence |
| RB | Pathology |
| RC | Practice of medicine |
| RD | Surgery |
| RE | Ophthalmology |
| RF | Otology. Phrenology. Laryngology |
| RG | Gynecology and obstetrics |
| RJ | Pediatrics |
| RK | Dentistry |
| RL | Dermatology |
| RM | Therapeutics |
| RS | Pharmacy and materia medica |
| RT | Nursing |
| RV | Botanic, Thomsonian and Eclectic medicine |
| RZ | Miscellaneous schools and arts |
| S | Agriculture. Plant and Animal Industry |
| | General agriculture, soils, fertilizers, farm implements, etc. |
| SB | General plant culture, including field crops. Horticulture. Landscape gardening and parks. Pests and diseases |
| SD | Forestry |
| SF | Animal husbandry. Veterinary medicine |
| | Fish culture and fisheries. Angling |
| SK | Hunting. Game protection |
| T | Technology. General |
| TA-TH | Building and Engineering Group |
| TA | Engineering. General. Civil engineering |
| TC | Hydraulic engineering (harbours, rivers, canals) |
| TD | Sanitary and municipal engineering |
| TE | Roads and pavements |
| TF | Railroads |
| TG | Bridges and roofs |
| TH | Building construction |
| | 9111-9600 Fire prevention, fire extinction |
| TJ-TL | Mechanical Group |
| TJ | Mechanical engineering |
| TK | Electric engineering and industries |
| TL | Motor vehicles. Cycles. Aeronautics |
| TN-TR | Chemical Group |
| TN | Mineral industries |
| TP | Chemical technology |
| TR | Photography |
| TS-TX | Composite Group |
| TS | Manufactures |
| TT | Trades |
| TX | Domestic science |
| U | Military Science. General |
| UA | Armies. Organization and distribution |
| UB | Administration |
| UC | Maintenance and transportation |
| UD | Infantry |
| UE | Cavalry |
| UF | Artillery |
| UG | Military engineering |
| UH | Minor services |
| V | Naval Science. General |
| VA | Navies. Organization and distribution |
| VB | Administration |
| VC | Maintenance |
| VD | Seamen |
| VE | Marines |
| VF | Ordnance |
| VG | Minor services |
| VK | Navigation |
| VM | Shipbuilding and marine engineering |
| Z | Bibliography and Library Science |
The following extracts from its valuable introduction will give the best view of the principles on which the system is based:
“The Order of the Main Classes.—The reasons which determined the adoption of a certain sequence of classes in this system may be briefly set forth here, instead of any argument or attempt to justify the order. The battle which has raged, and is still raging, among scientists, as to the best and most desirable order in which to arrange the great branches of human knowledge in order to produce a ‘hierarchy,’ must deter a non-scientific classifier from arguing on such a complicated and difficult topic. It will, therefore, suffice if I briefly describe the main classes in their order and give reasons why they were assigned to the places they occupy.