After the rout of the Murcians at Baza in Granada, he rallied the fugitives, and in virtue of his authority as regent assumed the chief direction of the war in Valencia, where his noble efforts were nearly rendered futile by the villainy of Palacio's faction, who opposed him and endeavoured to detach the soldiers and people from his authority, and proposed to inundate the plains that lie round the black marble mountain of Murviedro; but on Suchet invading the province, Blake concentrated his ill-armed and undisciplined but brave horde of peasantry to meet him. Exclusive of 5000 infantry and 700 Murcian horsemen, under O'Mahy, at Cuença, and 2000 men under Bassecour at Riguena, in September, he had 20,000 foot and 2000 horse; but, as a foreigner by name and race, he was unpopular both in Murcia and Valencia, "and the regency of which he formed a part was tottering," adds General Napier, in the fourth volume of his history. "The Cortes had quashed O'Mahy's command of the Murcian army, and even recalled Blake himself; but the order, which did not reach him until he was engaged with Suchet, was not obeyed. Meanwhile that part of the Murcian army which should have formed a reserve after O'Mahy's division had marched for Cuença, fell into the greatest disorder; above 8000 men deserted in a few weeks, and those who remained were exceedingly dispirited."

Suchet's army entered in three columns, passed Castellon de la Plana, masked Pensicola, invested Oropesa, and skirmished at Almansora, where a few French, by bravely routing a great body of Spaniards, made Blake doubt seriously the firmness of his troops; and thus leaving four thousand men under O'Donnel at Segorbe, he retired beyond the Guadalquiver, leaving Valencia in confusion. Suchet then invested the town of Saguntum, and again turning all his attention to destroy Blake, after much manœuvring, they fought their disastrous battle of the 25th October, 1811.

On the level and fertile plain which lies between Murviedro and Valencia, and is intersected by torrents and ravines, fringed by olive-trees, Suchet drew out his lines of battle before the ramparts of Saguntum, where Blake was defeated, with the loss of 5000 men; and on the Emperor Napoleon reinforcing Suchet with 15,000 men, under General Reille (a Reilly of Irish parentage), the position of Blake and his Andalusians became more than ever desperate.

He had now fought five pitched battles as a general, and had under his command 22,000 foot and 3000 horse. In November, Suchet advanced towards the Guadalquiver with a force diminished to 18,000 men by garrisons and detachments. Though Blake had destroyed two of the bridges, and manned the houses, and was in hourly expectation of a general rising of the Valencians, the French fearlessly stormed his defences, crossed the river, menaced his front, and harassed his rear, until he was compelled to form an intrenched camp five miles in extent, enclosing the city of Valencia and three of its suburbs. A twelve-feet ditch surrounded this camp, the slope of which was so high as to require ladders.

The battle of Valencia, fought in December, 1811, followed. O'Mahy was defeated, and fled to Alcira, leaving Blake blocked up in the fortified camp with eighteen thousand men in want of provisions, while the French were well and freely supplied by the Valencians, who, as Blake reports, "were a bad people." On the 2nd December he made a bold effort to break through Suchet's lines, and sallied out at the head of ten thousand men; but was repulsed, and Suchet pushed more vigorously than ever the siege of the city, knowing well that it was impossible for Blake to remain long in a camp which included a starving population of fifty thousand souls. The fire of sixty great guns drove Blake into the city, abandoning his camp on the 5th December to the foe, who found in it eighty pieces of cannon. In the evening Suchet summoned Valencia; but Blake declined to yield. Then skirmishes, assaults, and bombarding continued till the 9th, when the citizens were on the point of insurging against Blake, and insisted that he should surrender. He complained bitterly of their cowardice, and required leave to march with his soldiers to Alicant with their baggage, colours, and only four pieces of cannon.

These terms were refused him.

The Valencians opened their gates, and the brave but unfortunate Blake was compelled to surrender his sword, and march out at the head of twenty-two generals, eight hundred and ninety-three other officers, and eighteen thousand men, as prisoners of war; leaving in the hands of the enemy eighty stand of colours, two thousand horses, three hundred and ninety pieces of cannon, forty thousand stand of arms, one hundred and eighty thousand pounds of powder, and three millions of ball-cartridges, with a vast store of other warlike munition.

After the fall of Valencia he had no opportunity of achieving anything of importance; and in May, 1812, the Regent Charles O'Donnel, Conde de Abispal, bestowed the command of the Valencian forces upon his own brother Joseph, who rallied at Alicant the remains of Blake's army, four thousand of whom escaped from Suchet's guards.

For his last important capture, Suchet was created Duke of Albufera; and poor Blake, as a prisoner of war too important to be exchanged, was ordered into France with his two aides-de-camp.

The preceding has been but a brief outline of the career, services, and struggles of Blake, whose popularity, by a combination of circumstances over which he had no control, was almost destroyed for ever in Spain.