It must be recollected that we have distinguished coal in general as of two different species, one perfect or proper coal, containing no perceptible quantity of either oil or phlegm; the other as burning with smoke and flame, consequently containing both aqueous and oleaginous substances which it emits in distillation. It is the first of these which we are now to consider more particularly, in order to see the varieties which may be found in this species of mineral substance.
When that bituminous fossil, which is the common coal of this country, is submitted to heat it is subject to melt more or less, and emits smoke which is composed of water and oil. If it be thus completely distilled, it becomes a perfect coal of a porous or spongy texture. Such a substance as this is extremely rare among minerals; I have however found it. It is in the harbour of Ayr, where a whinstone dyke traverses the coal strata, and includes some of that substance in the state of coals or cinder. I pointed this out many years ago to Dr Black; and lately I showed it to Professor Playfair.
But the culm of South Wales, the Kilkenny coal of Ireland, and the blind coal of Scotland, notwithstanding that these are a perfect coal, or charred to a coal, have nothing of the porous construction of the specimen which I have just now mentioned; they are perfectly solid, and break with a smooth shining surface like those which emit smoke and flame.
Here is therefore a mineral operation in the preparation of those coals which we cannot imitate; and here is the clearest evidence of the operation of mineral fire or heat, although we are ignorant of the reason why some coal strata are charred, while others are not, and why, in some particular cases, the charred coal may be porous or spungy like our coaks, while in general those blind coals (as they are called) are perfectly solid in their structure.
But to what I would call more particularly the attention of mineral philosophers is this, that it is inconceivable to have this effect produced by means of water; we might as well say that heat were to be the cause of ice. The production of coal from vegetable bodies, in which that phlogistic substance is originally produced, or from animal bodies which have it from that source, is made by heat, and by no other means, so far as we know. But, even heat alone is not sufficient to effect that end, or make a perfect coal; the phlogistic body, which is naturally compound, consisting of both inflammable and combustible substances, must be separated chemically, and this must be the operation of heat under the proper circumstances for distillation or evaporation.
Here is the impossibility which in the last chapter I have alleged the aqueous theory has to struggle against; and here is one of the absolute proofs of the igneous theory. Not only must the aqueous part of those natural phlogistic bodies be evaporated, in order to their becoming coal, but the oily parts must also, by a still increased degree of heat, be evaporated, or separated by distillation from the combustible part. Here, therefore, is evidently the operation of heat, not simply that of fusion in contradiction to the fluidity of aqueous solution, but in opposition to any effect of water, as requiring the absence or separation of that aqueous substance.
But those natural appearances go still farther to confirm our theory, which, upon all occasions, considers the compression upon the bodies that are submitted to the operation of heat, in the mineral regions, as having the greatest efficacy in modifying that operation. Coal strata, which are in the neighbourhood of each other, being of those two opposite species, the one fusible and inflammable, the other infusible and combustible, afford the clearest proof of the efficacy of compression; for, it is evident, that the coal, which was once bituminous or fusible, cannot be charred without the distillation of that substance; therefore, prevent the distillation by compression and the charring operation cannot proceed, whatever should be the intensity of the heat; and then, fusion alone must be the effect upon the bituminous body. But now, as we have both those species of coal in the vicinity of each other, and even the same strata of coal part charred, while the rest is not, this natural appearance, so far from being a stumbling block, as it must be to the opposite theory, is most clearly explained by the partial escape of vapours from the mineral regions, and thus confirms the theory with regard to the efficacy of compression.
It is owing to the solidity of those natural charred coals, and the want of oil, that they are so very difficult of kindling; but, when once kindled in sufficient quantity, they make a fire which is very durable. There are even some of them which, to common observation, seem to be altogether incombustible. I have of this kind a specimen from a stratum at Stair, which shall be afterwards mentioned.
M. Struve, in the Journal de Physique for January 1790, describes a mineral which he calls plombagine charbonneuse ou hexaëdre; and gives for reason, parce qu'elle ressemble extrêmement au charbon de pierre schisteux, ou d'hexaëdre. He says farther, "Il est très commun, dans une roche qui forme un passage entre les granits et les brèches, qu'on n'a trouvée jusqu'à présent qu'on masses roulées dans le pays de Vaud." He concludes his paper thus: "Ce fossile singulier ne paroît pas appartenir à la Suisse seule. J'ai dans ce moment devant les yeux une substance parfaitement semblable, si on excepte la couleur qui tient le milieu entre le gris de fer et le rouge modéré; elle vient du pays de Gotha de la Friedrischs-grube, proche d'Umneau. On le regarde comme un eisenrahm uni à du charbon de pierre."
The specimen which I have from Stair upon the water of Ayr, so far as I can understand, perfectly resembles this plombagine of M. Struve. It consumes very slowly in the fire, and deflagrates like plumbago with nitre. Now this comes from a regular coal stratum; and what is more remarkable, in this stratum is contained a true plumbago, Farther up the country, the Earl of Dumfries has also a mine containing plumbago along with other coal strata; and though the plumbago of these two mines have not all the softness and beauty of the mineral of the same species from Cumberland, they are nevertheless perfect plumbago.