The iron surface to be treated should first be thoroughly cleansed, and then immediately put into a tank containing a cyanide of copper solution. Two forms of copper solution are used, namely, the cyanide, which is a salt solution of copper, and the sulphate, which is an acid solution of copper. Cyanide is first used because it does not attack the iron, as would be the case if the sulphate solution should first come into contact with the iron.
A sheet of copper, termed the anode, is then placed within the tank, parallel with the surface to be plated, known as the cathode, and so mounted that it may be adjusted to or from the iron surface, or cathode. A direct current of electricity is then caused to flow through the copper plate and into the iron plate or surface, and the plating proceeded with until the iron surface has a thin film of copper deposited thereon. This is a slow process with the cyanide solution, so it is discontinued as soon as possible, after the iron surface has been completely covered with copper. This copper surface is thoroughly cleaned off to remove therefrom the saline or alkaline solution, and it is then immersed within a bath, containing a solution of sulphate of copper. The current is then thrown on and allowed so[p. 134] to remain until it has deposited the proper thickness of copper.
Direction of Current.—If a copper and an iron plate are put into a copper solution and connected up in circuit with each other, a primary battery is thereby formed, which will generate electricity. In this case, the iron will be positive and the copper negative, so that the current within such a cell would flow from the iron (in this instance, the anode) to the negative, or cathode.
The action of electroplating reverses this process and causes the current to flow from the copper to the iron (in this instance, the cathode).
CHAPTER XIV[ToC]
ELECTRIC HEATING, THERMO ELECTRICITY
Generating Heat in a Wire.—When a current of electricity passes through a conductor, like a wire, more or less heat is developed in the conductor. This heat may be so small that it cannot be measured, but it is, nevertheless, present in a greater or less degree. Conductors offer a resistance to the passage of a current, just the same as water finds a resistance in pipes through which it passes. This resistance is measured in ohms, as explained in a preceding chapter, and it is this resistance which is utilized for electric heating.
Resistance of Substances.—Silver offers less resistance to the passage of a current than any other metal, the next in order is copper, while iron is, comparatively, a poor conductor.