In the middle ages this plant was called varantia, a name which must have arisen from verantia. The latter means the real, genuine dye; as aurantia signified a golden yellow. Till the year 1736, this plant was little regarded, except among dyers, farmers and merchants, who purchased it from the farmers, in order to sell it to the dyers with profit; and among a few herb-dealers and physicians, who, on the authority of the ancients, ascribed to it eminent virtues, which others doubted or altogether denied. In the above year, however, a property of it was discovered by accident, as usual, which rendered it an object of more attention. John Belchier, an English surgeon, having dined with a cotton-printer, observed that the bones of the pork which was brought to the table were red. As he seemed surprised at this circumstance, his host assured him that the redness was occasioned by the swine feeding on the water mixed with bran in which the cotton cloth was boiled, and which was coloured by the madder used in printing it. Belchier[276], to whom this effect was new, convinced himself by experiments that the red colour of the bones had arisen from the madder employed in printing the cotton, and from no other cause; and he communicated his discovery to the Royal Society, in a paper which was printed in their Transactions.
This singularity was now soon known to all the naturalists, several of whom made new experiments, the result of which brought to light many truths useful to physiology. Besides the roots of madder, those of the Galium (yellow ladies-bed-straw) and other plants which have an affinity to madder, produce the like effects; but this is the case neither with saffron nor woad, nor with many others much used in dyeing. The colouring takes place soonest in young animals; and is strongest where the bones are hardest and thickest. On the other hand, it does not reach the soft parts; appears only a little in the milk; and in general is not perceptible in the animal juices[277].
As the English calico-printers were acquainted with this effect of madder before it was known to naturalists, it is not improbable that it was known much sooner in other places, where the plant has been much cultivated and used since the earliest periods. From what J. E. Stief says, we have reason to believe that the people in the neighbourhood of Breslau, his native city, who gave the stalks of the madder plant to their cows instead of straw, must have first discovered that it possessed the property of communicating a red colour to the bones[278].
As many truths not yet investigated by means of new experiments, and which on that account have not yet been acknowledged, are concealed among the evidently false assertions to be found in the works of the ancients, and as these works were thrown aside too early, before their contents were properly examined, I was induced to suspect that some hints of this colouring property might also be mentioned in them, which indeed is the case.
We learn from the works of Galen and Dioscorides, that the ancient physicians remarked that the use of certain roots, which they administered to their patients, communicated a colour to their urine and excrements; and this observation has been repeated by Cardan, Thurneisser, Porta, Castor, Durantes, and others. Had those ancient physicians, who often prescribed these roots, and paid attention to the colour of the excrements of their patients, been accustomed to open their bodies when they died under their hands, they would have perhaps remarked, in human bones, what was observed long after in the bones of animals, when the roots were no longer used in medicine; and what, if I am not mistaken, was never yet observed in the bones of the human species[279].
Böhmer, who made researches respecting the antiquity of this observation, found it neither in Rombert. Dodonæus, Mich. Ettmuller, Morin, Will. Salmon, nor others, who, however, speak of coloured urine. In his opinion the oldest writer who speaks of coloured bones is Mizaldus; but what he relates is all taken from the treatise of Lemnius De Miraculis Occultis Naturæ; and the latter therefore is the oldest writer that I at present can mention as acquainted with this property. He was a physician in Zealand, where madder has been cultivated since the earliest ages, and where he had an opportunity of remarking it. He says that the bones of animals became red, as had been observed when the flesh was dressed, by their eating only the leaves, and not the roots. In the first edition of the above work, printed in octavo, in the year 1559, which consists of two books, this information will not be found; but it may be contained in the second of 1564, which comprehends four books.
[The madder plant is much cultivated in Holland, but Macquei observes that the Dutch were first indebted to the Flemish refugees for their knowledge of the method of preparing this plant. Its culture has often been attempted in England, but always without success[280]. It is also largely cultivated in Alsace and Provence in France, especially near Avignon, in Asiatic Turkey, and in Italy; from which places it is largely exported. The Turkey and Provence madder is procured from Rubia peregrina; the remainder from R. tinctorum. To prepare the root, which is the part used in dyeing, it is removed from the ground, picked, dried and ground.
Madder contains three distinct colouring principles; two of these are red, viz. alizarine and purpurine, and one, xanthine, is yellow.
Since 1836, two new products have been introduced into commerce, which are destined to replace madder in the operations of dyeing and calico-printing; one is called garancine, the other colorine. Garancine is prepared by washing and macerating madder, and filtering through linen. The grounds are then crushed and mixed with sulphuric acid, equal to half the amount of madder first employed; the acid should be somewhat dilute. It is then poured hot upon the madder, agitated, and when the mixture appears intimate, the temperature is raised to 212°, and maintained for about an hour. It is then again mixed with water, filtered, and thoroughly washed. It is finally pressed, dried and passed through the sieve. This is the process patented by MM. Lagier, Robiquet and Colin, in 1828.
It was first introduced into commerce by the house of Lagier and Thomas, at Avignon, in 1829.