Catoptrical colours are such as appear in consequence of a mirror-like reflection. We assume, in the first place, that the light itself as well as the surface from which it is reflected, is perfectly colourless. In this sense the appearances in question come under the head of physical colours. They arise in consequence of reflection, as we found the dioptrical colours of the second class appear by means of refraction. Without further general definitions, we turn our attention at once to particular cases, and to the conditions which are essential to the exhibition of these phenomena.
If we unroll a coil of bright steel-wire, and after suffering it to spring confusedly together again, place it at a window in the light, we shall see the prominent parts of the circles and convolutions illumined, but neither resplendent nor iridescent. But if the sun shines on the wire, this light will be condensed into a point, and we perceive a small resplendent image of the sun, which, when seen near, exhibits no colour. On retiring a little, however, and fixing the eyes on this refulgent appearance, we discern several small mirrored suns, coloured in the most varied manner; and although the impression is that green and red predominate, yet, on a more accurate inspection, we find that the other colours are also present.
If we take an eye-glass, and examine the appearance through it, we find the colours have vanished, as well as the radiating splendour in which they were seen, and we perceive only the small luminous points, the repeated images of the sun. We thus find that the impression is subjective in its nature, and that the appearance is allied to those which we have adverted to under the name of radiating halos ([100]).
We can, however, exhibit this phenomenon objectively. Let a piece of white paper be fastened beneath a small aperture in the lid of a camera-obscura, and when the sun shines through this aperture, let the confusedly-rolled steel-wire be held in the light, so that it be opposite to the paper. The sun-light will impinge on and in the circles of the wire, and will not, as in the concentrating lens of the eye, display itself in a point; but, as the paper can receive the reflection of the light in every part of its surface will be seen in hair-like lines, which are also iridescent.