An investigation into the chemical activity of the pile led Davy to the discovery of a new series of facts, to which we find an allusion in his former letters to Mr. Gilbert, and which subsequently formed the basis of his first communication read before the Royal Society on the 18th of June in the same year.
All the combinations analogous to the Voltaic pile had hitherto consisted of a series containing, at least, two metallic bodies, (or one metal and charcoal,) and a stratum of fluid. Davy discovered that an accumulation of galvanic energy, exactly similar to that in the common pile, might be produced by the arrangement of single metallic plates with different strata of fluids; so that, instead of composing a battery with two metals and one fluid, he succeeded in constructing it with one metal and two fluids; provided always that oxidation, or some equivalent chemical change, should proceed on one of the metallic surfaces only.
In describing these combinations of a single metal with two fluids, he divides them into three classes, following in the arrangement the order of time with regard to their discovery.
In the First Class, one side of the metallic plate is oxidated; in the Second, a sulphuret is formed on one of its surfaces; and in the Third, both sides are acted upon, the metal becoming a sulphuret on one of its surfaces, and an oxide on the other.
The apparatus which he employed for these experiments is preserved in the laboratory of the Royal Institution. It consists of a trough, containing grooves capable of receiving the edges of the different plates necessary for the arrangement, one half of which are composed of horn, the other half of some one metal.
When the apparatus was used, the cells were filled, in the galvanic order, with the different solutions, according to the class of the combination, and connected in pairs with each other by slips of moistened cloth carried over the non-conducting plates.
At the meeting of the Royal Society, following that on which the above interesting facts were communicated, Dr. Wollaston presented a memoir of considerable importance, entitled, "Experiments on the Chemical Production and agency of Electricity;" in which he strongly advocates the truth of that theory which recognises metallic oxidation as the primary cause of the Voltaic phenomena. This paper is also farther important as it proves, by most ingeniously devised experiments, not only the similarity of the means by which both common and galvanic electricity are excited, but also the resemblance existing between their effects; showing, in fact, that they are both essentially the same, and confirming the opinion, that all the apparent differences may depend upon differences in intensity and quantity.
Acting upon this principle, Dr. Wollaston succeeded in producing a very close imitation of the chemical action of galvanism by common electricity; such, for example, as the decomposition of water, and other effects of oxidation and deoxidation.[60] In the prosecution of this train of research, he displays, in a very striking manner, that attention to minute arrangement which so remarkably characterised all his manipulations. I particularly allude to the expedients by which he reduced the extremity of a gold wire, in order to apportion the strength of the electric charge to the quantity of water submitted to its influence.
Although it is now very generally admitted, that the chemical agency of the fluids upon the metals employed is highly essential to the maintenance of Voltaic action, there still remains considerable doubt as to how far we are entitled to regard it as the first in the order of phenomena.
At a later period of his researches, Davy suggested as a correction, or rather modification, of the