The following are the principal authorities for the quantity of oxygen in zinc oxide, in the order of time.

Zinc. Oxygen
1766.Cavendish 100 + 23.3
1785.Lavoisier— + 19.6
1790-1800.Wenzel and Proust— + 25
1801.Desorme and Clement— + 21.7
Davy— + 21.95
Berzelius— + 24.4
Gay Lussac— + 24.4
Thomson— + 24.42
My own— + 24

Now if 24 oxy. ∶ 100 zinc ∷ 7 oxy. ∶ 29 zinc, nearly, which is therefore the weight of an atom of this metal, on the supposition that the oxide is 1 oxygen and 1 metal; and the atom of oxide = 36.

I formerly estimated the atom of zinc at 56 (Vol. 1, page 260). This was occasioned by taking the above as the deutoxide instead of the protoxide. By violently heating the oxide of zinc in a close vessel, Desorme and Clement reduced the oxygen nearly one half, so as to afford a presumption that an oxide with half the oxygen of the common one subsisted. Since that time some observations of Berzelius seem to shew that a suboxide of zinc exists. It does not appear however, that such oxide is ever found in combination with acids; and, granting the accuracy of the observations, it is rather to be presumed to be the semi-oxide, or 1 atom of oxygen and 2 of metal, than the protoxide. No higher oxidation of zinc than the above has yet been obtained, and probably does not exist.

15. Oxides of potassium.

Since writing the articles “potassium and sodium,” in the former volume, a very important essay relating chiefly to these subjects has been written by Gay Lussac and Thenard (a copy of which they were so good as to send me), entitled “Recherches Physico-chimiques, &c.” in 2 Vol.—Many of the most interesting experiments of Davy have been repeated on a larger scale, and a great number of original ones added; these ingenious authors endeavour to sum up the evidences for and against the two hypotheses concerning potassium and sodium, namely, as to their being metals or hydrurets, and upon the whole incline to the former, allowing however, that the facts afford great plausibility to both. One thing they seem to have discovered and established, that the new bodies or metals admit of various degrees of oxidation, and of course these products have a claim to be classed amongst oxides in general though the nature of their bases may still be an object of dispute.

They find three oxides of potassium; the lowest degree is obtained by exposing potassium to atmospheric air in a small bottle, with a common cork; a gradual oxidation takes place; a blueish grey brittle product is obtained; there does not appear however, to be any proper limit to this oxidation besides that which they admit as characterizing the second degree or potash, which degree of oxidation may always be immediately obtained by placing potassium in contact with water. This I think should be called the protoxide and considered as 1 atom of potassium, and 1 of oxygen; before this point it is potassium and potash mixed or perhaps combined.

Besides these there is another obtained by burning potassium in oxygen gas at an elevated temperature; this oxide is yellow, fusible by heat, and crystallizes in lamina on cooling; it contains three times as much oxygen as potash; put into water it is suddenly decomposed, giving out ⅔ of the oxygen in gas and becoming potash. Very probably an oxide containing twice as much oxygen as potash might be formed with some mark of discrimination, by uniting 18 parts potassium with 56 of yellow oxide, but this has not yet been done.

According to these conclusions the weights of the oxides of potassium may be stated as under.—Potassium 35, protoxide or potash 42, deutoxide (supposed to exist) 49, and the yellow or tritoxide 56. Hence we have

Potassium. Oxygen
Protoxide (potash)100 + 20Gay Lussac & Thenard
19Davy
Deutoxide100 + 40 (unknown)
Tritoxide100 + 60 Gay Lussac & Thenard