| Dalton— | 1 atom sulphate of potash. |
| 4 atoms sulphate of alumine. | |
| 30 atoms water. | |
| Phillips— | 1 atom bisulphate of potash. |
| 2 atoms sulphate of alumine. | |
| 22 atoms water. | |
| Thomson— | 1 atom sulphate of potash. |
| 3 atoms sulphate of alumine. | |
| 25 atoms water. | |
Notwithstanding these differences, there is a near approximation in all three, in regard to the quantities of acid, alumine, potash, and water in the salt. This is accounted for partly in the different relative weights of the atoms, as estimated by the different analysts, but chiefly in that of alumine.
Some very curious results occurred to me about 10 years ago in analysing alum; they were new to me, but I have since found they had been previously discovered by Scheele. (See his essay on silex, clay, and alum, 1776.) As his observations are not to be found in any of our elementary books that I have seen, I shall give the particulars of my own experiments here.
I take 24 grains of alum and dissolve them in water; of these 8 grains may be allowed for sulphuric acid, ⅕ of which = 1.6 grain = 1.1 grain of lime = 880 grains of lime water, such as I commonly use. To the solution of alum I put 880 grains of lime water; a slight precipitate appears which soon becomes redissolved almost completely. The liquid is then acid by the colour test.
To this liquid I put 880 more of lime water, and agitate; a copious precipitate appears and continues; after subsidence the clear liquid is still acid by the colour test.
Another 880 grains are added, and the whole is then well agitated; the agitation is repeated two or three times after the precipitate has partly subsided, so as to diffuse it equally again through the liquid; finally, the clear liquid is found to be neutral by the colour test, and to contain no alumine; for, lime water produces no precipitate when poured into it.
Another 880 grains being added, and the whole stirred well, the clear liquid after the subsidence of the precipitate is still neutral by the colour test.
The fifth portion of 880 grains being then added, and the mixture well agitated, a considerable portion of the precipitate will evidently disappear, and the mixture become semitransparent; after a time the clear supernatant liquid is found strongly alkaline; a little of it touched with an acid becomes milky, and adding more acid clears it again. The liquid is now 1.0025 sp. gr., or a little heavier than lime water.
The sixth portion of 880 grains being now added to the whole mixture, and agitated, the precipitate rather diminishes, and an increase of specific gravity takes place in the liquid; it is now 1.003.
The seventh and last portion of 880 grains being added to the mixture, and agitation being continued for some time, a dense bulky precipitate is formed, which falls with great celerity, carrying with it the greatest part of the acid, the alumine and the lime, and leaving the liquid of the sp. gr. 1.0012. It is a subsulphate into which acid, potash, lime and alumine enter, as will be shewn.