(344.) One of the chief agents in chemistry, on whose proper application and management the success of a great number of its enquiries depends, and many of whose most important laws are disclosed to us by phenomena of a chemical nature, is HEAT. Although some of its effects are continually before our eyes as matters of the most common occurrence, insomuch that there is scarcely any process in the useful arts and manufactures which does not call for its intervention, and although, independent of this high utility, and the proportionate importance of a knowledge of its nature and laws, it presents in itself a subject of the most curious speculation; yet there is scarcely any physical agent of which we have so imperfect a knowledge, whose intimate nature is more hidden, or whose laws are of such delicate and difficult investigation.
(345.) The word heat generally implies the sensation which we experience on approaching a fire; but, in the sense it carries in physics, it denotes the cause, whatever it be, of that sensation, and of all the other phenomena which arise on the application of fire, or of any other heating cause. We should be greatly deceived if we referred only to sensation as an indication of the presence of this cause. Many of those things which excite in our organs, and especially of those of taste, a sensation of heat, owe this property to chemical stimulants, and not at all to their being actually hot. This error of judgment has produced a corresponding confusion of language, and hence had actually at one period[55] crept into physical philosophy a great many illogical and absurd conclusions. Again, there are a number of chemical agents, which, from their corroding, blackening, and dissolving, or drying up the parts of some descriptions of bodies, and producing on them effects not generally unlike (though intrinsically very different from) those produced by heat, are said, in loose and vulgar language, to burn them; and this error has even become rooted into a prejudice, by the fact that some of these agents are capable of becoming actually and truly hot during their action on moist substances, by reason of their combination with the water the latter contain. Thus, quicklime and oil of vitriol both exercise a powerful corrosive action on animal and vegetable substances, and both become violently hot by their combination with water. They are, therefore, set down in vulgar parlance as substances of a hot nature; whereas, in their relations to the physical cause of heat, they agree with the generality of bodies similarly constituted.
(346.) The nature of heat has hitherto been chiefly studied under the general heads of—
1st, Its sources, or the phenomena which it usually accompanies.
2d, Its communication from its sources to substances capable of receiving it, and from these to others, with a view to discover the laws which regulate its distribution through space or through the bodies which occupy it.
3d, Its effects, on our senses, and on the bodies to which it is communicated in its various degrees of intensity, by which, means are afforded us of measuring these degrees.
4th, Its intimate relations to the atoms of matter, as exhibited in its capability of acquiring a latent state under certain circumstances, and of entering into something like chemical combinations.
(347.) The most obvious sources of heat are, the sun, fire, animal life, fermentations, violent chemical actions of all kinds, friction, percussion, lightning, or the electric discharge, in whatever manner produced, the sudden condensation of air, and others, so numerous, and so varied, as to show the extensive and important part it has to perform in the economy of nature. The discoveries of chemists, however, have referred most of these to the general head of chemical combination. Thus, fire, or the combustion of inflammable bodies, is nothing more than a violent chemical action attending the combination of their ingredients with the oxygen of the air. Animal heat is, in like manner, referable to a process bearing no remote analogy to a slow combustion, by which a portion of carbon, an inflammable principle existing in the blood, is united with the oxygen of the air in respiration; and thus carried off from the system: fermentation is nothing more than a decomposition of chemical elements loosely united, and their re-union in a more permanent state of combination. The analogy between the sun and terrestrial fire is so natural as to have been chosen by Newton to exemplify the irresistible force of an inference derived from that principle. But the nature of the sun and the mode in which its wonderful supply of light and heat is maintained are involved in a mystery which every discovery that has been made either in chemistry or optics, so far from elucidating, seems only to render more profound. Friction as a source of heat is well known: we rub our hands to warm them, and we grease the axles of carriage-wheels to prevent their setting fire to the wood; an accident which, in spite of this precaution, does sometimes happen. But the effect of friction, as a means of producing heat with little or no consumption of materials, was not fully understood till made the subject of direct experiment by count Rumford, whose results appear to have established the extraordinary fact, that an unlimited supply of heat may be derived by friction from the same materials. Condensation, whether of air by pressure, or of metals by percussion, is another powerful source of heat. Thus, iron may be so dexterously hammered as to become red-hot, and the rapid condensation of a confined portion of air will set tinder on fire.
(348.) The most violent heats known are produced by the concentration of the solar rays by burning glasses,—by the combustion of oxygen and hydrogen gases mixed in the exact proportion in which they combine to produce water,—and by the discharge of a continued and copious current of electricity through a small conductor. As these three sources of heat are independent of each other, and each capable of being brought into action in a very confined space, there seems no reason why they might not all three be applied at once at the same point, by which means, probably, effects would be produced infinitely surpassing any hitherto witnessed.
(349.) Heat is communicated either by radiation between bodies at a distance, or by conduction between bodies in contact, or between the contiguous parts of one and the same body. The laws of the radiation of heat have been studied with great attention, and have been found to present strong analogies with that of light in some points, and singular differences in others. Thus, the heat which accompanies the sun’s rays comports itself, in all respects, like light; being subject to similar laws of reflection, refraction, and even of polarization, as has been shown by Berard. Yet they are not identical with each other; Sir William Herschel having shown, by decisive experiments, verified by those of Sir H. Englefield, that there exist in a solar beam both rays of heat which are not luminous, and rays of light which have no heating power.
(350.) The heat, radiated by terrestrial fires, and by bodies obscurely hot, by whatever means they have acquired their heat (even by exposure to the sun’s rays), differs very materially from solar heat in their power of penetrating transparent substances. This singular and important difference was first noticed by Mariotte, and afterwards made the subject of many curious and interesting experiments by Scheele, who found that terrestrial heat, or that radiated from fires or heated bodies, is intercepted and detained by glass or other transparent bodies, while solar heat is not; and that, being so detained, it heats them: which the latter, as it passes freely through them, is incapable of doing. The more recent researches of Delaroche, however, have shown that this detention is complete only when the temperature of the source of heat is low; but that, as that temperature is higher, a portion of the heat radiated acquires a power of penetrating glass; and that the quantity which does so bears continually a larger and larger proportion to the whole, as the heat of the radiant body is more intense. This discovery is very important, as it establishes a community of nature between solar and terrestrial heat; while at the same time it leads us to regard the actual temperature of the sun as far exceeding that of any earthly flame.
(351.) A variety of theories have been framed to account for these curious phenomena; but the subject stands rather in need of further elucidation from experiment, and is one which merits, and will probably amply repay, the labours of those who may hereafter devote their attention to it. The theory of the radiation of heat, in general, which seems to agree best with the known phenomena, is that of M. Prevost, who considers all bodies as constantly radiating out heat in all directions, and receiving it by a similar means of communication from others, and thus tending, in any space filled, wholly or in part, with bodies at various temperatures, to establish an equilibrium or equality of heat in all parts. The application of this idea to the explanation of the phenomenon of dew we have already seen (see [167].). The laws of such radiation, under various circumstances, have been lately investigated in a beautiful series of experiments on the cooling of bodies by their own radiation in vacuo, by Messrs. Dulong and Petit, which offer some of the best examples in science of the inductive investigation of quantitative laws.
(352.) The communication of heat between bodies in contact, or between the different parts of the same body, is performed by a process called conduction. It is, in fact, only a particular case of radiation, as has been explained above (217.); but a case so particular as to require a separate and independent investigation of its laws. The most important consideration introduced into the enquiry by this peculiarity is that of time. The communication of heat by conduction is performed, for the most part, with extreme slowness, while that performed by direct radiation is probably not less rapid than the propagation of light itself. The analysis of the delicate and difficult points which arise in the investigation of this subject in its reduction to direct geometrical treatment has been executed with admirable success by the late Baron Fourrier, whose recent lamented death has deprived science of an ornament it could ill spare, thinned as its ranks have been within the last few years. This acute philosopher and profound mathematician has developed, in a series of elaborate memoirs presented to the French Institute, the laws of the communication of heat through the interior of solid masses, placed under the influence of any external heating and cooling causes, and has in particular applied his results to the conditions on which the maintenance of the actual observed temperature on the earth’s surface depends; to the possible influence of a supposed central heat on our climates; and to the determination of the actual amount of the heat, derived to us from the sun, or at least that portion of it on which the difference of the seasons depends.