In 1884 he travelled in Spain and Algeria, and in 1885 married Ethel, daughter of Major-General Sir Henry Durand.

It was in January, 1887, that the English public were interested in the proposed expedition for the relief of Emin Pasha—Gordon's friend—under the command of H. M. Stanley. The whole idea was one that appealed to Jameson's chivalrous nature, and as it seemed to offer good opportunities for collecting specimens of big game, birds and insects in a part of Africa that was practically unknown, he offered a thousand pounds to be allowed to accompany the expedition as an officer acting under Stanley's orders. This offer was at once accepted.

"Why all the ambitions of my lifetime should have been concentrated at this time, with a seemingly prosperous issue, I know not; but I assure you that I did not accept the position without weighing well all there was for and against it. Ever since childhood I have dreamt of doing some good in this world, and making a name which was more than an idle one. My life has been a more or less selfish one, and now springs up this opportunity of wiping off a little of the long score standing against me. Do not blame me too much."[24]

After a wearisome journey up the Congo, Stanley decided to make a base camp at Yambuya on the Aruwimi, and to leave there all the sick and useless Soudanese and Zanzibari soldiers and porters, extra stores, etc., and to push on himself to the Ituri forest and Lake Albert with the main expedition. Two officers had to be left in charge at Yambuya, and to his great disgust Jameson found that he was one of those selected for this uncongenial task. Almost from the first the whole outfit suffered from semi-starvation. The site of the camp was badly chosen, the natives were more or less hostile, and Jameson and his gallant friend, Major Barttelot, were often at their wits' ends to feed their men and keep down the continuous death-rate.

Stanley, it seems, had promised to return in November, and that if he did not return he had arranged with Tippu-Tib, the Arab chieftain, ivory and slave-trader, and actual master of the Upper Congo, to permit a thousand porters to bring on the rearguard and join him at Lake Albert.

At last things became so desperate that Jameson himself went up the Congo, a twenty-four days' journey, to see Tippu-Tib to try and induce him to supply the men with which to cross Africa—even offering a bond for five thousand pounds on his and Major Barttelot's private account if Stanley's word was not considered sufficient. Tippu-Tib seems to have behaved well, and accompanied Jameson back to Stanley Falls, from which he and Barttelot presently started with some four hundred unruly Manyema savages.

We need not follow poor Jameson's troubles in the ensuing months of June to August, 1888, when, the move failing, owing to ceaseless thefts, desertions and small-pox, Jameson at last reached Unaria and Barttelot returned to Stanley Falls. Barttelot was then murdered, and Jameson returned to Stanley Falls, where he found it impossible to re-organize the expedition without monetary help, which at the time he could not obtain. There being no prospect of doing anything in the way of crossing Africa, and no word or orders having been received from Stanley, Jameson then went down the river to Bangala in order to obtain some reply from the Emin Relief Committee. Tippu-Tib indeed offered himself to go with Jameson, but demanded £20,000—a sum which at the time it was not possible for Jameson to guarantee. On this journey Jameson got wet and caught a chill which soon developed into acute fever. He was a dying man when his good friend Herbert Ward lifted him from the canoe at Bangala, and he only lived for a few days.

Jameson was to all who knew him well of a generous and gentle nature, full of thought for others and a man of high courage.

At the end of May, 1880, Selous reached Bulawayo and met his friends, and left a few days later for the hunting veldt, where they had fine sport with all sorts of game except elephants. On July 24th Jameson and Selous left their waggons on the Umfule river and went in on foot with thirteen natives into the "fly" country to the north. This was a rough, hilly country where rhinoceros were numerous in the hills and hippopotami in the river. The country was quite unknown, but the object of the hunters was to strike east to the Hanyane and follow it down to the Portuguese town of Zumbo on the Zambesi. At Lo Magondi's kraal they decided to abandon the Hanyane route and to follow the Umfule to its junction with the Umniati.

On July 31st they reached a pool and killed several hippopotami, and the hunters and natives were soon revelling in meat and fat. The next day Selous killed a very fine buffalo bull. In a few days they reached the Umniati and entered the first Banyai village. The party got game almost every day, and on August 10th Selous killed another fine buffalo bull. On the Umniati the natives engaged in the practice of enclosing a space of the river over 200 yards broad and 400 yards in length to confine a herd of hippopotami so as to starve them to death. In one of these the travellers saw ten unfortunate animals which had been enclosed for about three weeks. Occasionally one was speared by the natives when it became exhausted.