Sulphuric acid, HO,SO3, or oil of vitriol, is made in such enormous quantities that it is never worth while to attempt its preparation on a small scale. In consequence of its great affinity for water, many energetic changes are produced by its action. Oil of vitriol poured on some loaf sugar placed in a breakfast-cup with the addition of a dessert-spoonful of boiling water, rapidly boils and deposits an enormous quantity of black charcoal. If a word be written on a piece of white calico with dilute sulphuric acid, and then rapidly and thoroughly washed out, no visible change occurs; but if the calico is exposed to heat, so that the excess of water is driven off, the remaining and now concentrated oil of vitriol attacks the calico, and the word is indelibly printed in black by the decomposition of the fabric of cotton. A very remarkable process has lately been introduced by Mr. Warren de la Rue, by which paper is converted into a sort of tough parchment-like material, called ametastine, by the action of oil of vitriol and water of a certain fixed strength; and any departure from the exact proportions destroys the toughness of the paper. After the paper has been acted upon by the acid, it becomes extremely tenacious, and will support a considerable weight without breaking. Mr. Smee has used this ametastine in the construction of an hygrometer, and states that it may save many a traveller from catching a severe rheumatism in a damp bed.
Sixth Experiment.
When the vapour of sulphur is passed over red-hot charcoal and the product carefully condensed, a peculiar liquid is obtained, called bisulphide of carbon (CS2), which possesses a peculiar odour, is extremely transparent and brilliant-looking, and enjoys a high refractive power. This liquid is used as a solvent for phosphorus and other substances, and is extremely volatile and combustible, and burns silently with a pale blue flame. The combustion of its vapour, mixed with certain gases, offers a good example of the fact that slow burning may be a peaceful experiment, whilst very rapid combustion often resolves itself into an explosion. Thus, if a few drops of bisulphide of carbon are dropped into a narrow-mouthed dry quart bottle containing common air, and flame applied, the combustion takes place with rapidity, a rushing or roaring sound being audible, in consequence of the diffused vapour being supplied with more oxygen, and burning more rapidly than it would do if simply consumed from a stick or glass rod wetted with the fluid. A still greater rapidity of combustion is ensured by dropping some bisulphide of carbon into a long stout cylindrical jar, fifteen inches long and three inches in diameter, containing nitric oxide gas (NO2); when flame is applied the mixture burns with a bright flash and some noise, and if burnt in a narrow mouthed bottle would most likely blow it to atoms.
The greatest rapidity of combustion, and of course the loudest noise, is obtained by shaking some bisulphide of carbon in a similar stout and strong cylindrical jar filled with oxygen gas, but in this case the jar must be protected with a double cylinder of stout wire gauze; it does not always break, but if it is blown to fragments each particle becomes a lancet-shaped piece of glass, which is capable of producing the most dangerous wounds. (Fig. 152.)
Fig. 152.
a. Air and bisulphide of carbon. b. Nitric oxide and ditto. c. Oxygen and ditto. d d. Stout cylinder of double wire gauze, open top and bottom.
SELENIUM.
Selenium (σεληνη, the Moon[B]); symbol, Se; combining proportion, 39.5.
This new metallic element is allied to sulphur, and is a species of chemical curiosity, being found in minute quantities in various minerals; it may be melted and cast into any form. Medallions of the discoverer (Berzelius) of selenium, in little cases, are imported from Germany, for the cabinets of the curious.