The Boy's Playbook of Science / Including the Various Manipulations and Arrangements of Chemical and Philosophical Apparatus Required for the Successful Performance of Scientific Experiments in Illustration of the Elementary Branches of Chemistry and Natural Philosophy

by John Henry Pepper

Eleventh Experiment.

To silver electrotypes or other brass and copper articles, the first attention must be paid to the cleanness of them; and when an electrotype is just removed from the copper solution, and washed in clean water, it is at once ready to receive the coating of silver; otherwise, if it has been handled, or is slightly greasy, it should be first boiled in a solution of common washing soda, and then the oxide removed by passing it rapidly in and out of some "Dipping Acid," which is prepared by mixing together equal parts of oil of vitriol and nitric acid; when removed from the "Dipping Acid," it must be well washed in water, and may remain under the surface of the water until the silvering solution is ready. A silver solution may be prepared by dissolving a sixpence in some nitric acid contained in a flask; it is then poured into a solution of common salt, which precipitates the chloride of silver, and leaves the copper in solution—the latter is poured off when the chloride has subsided, and after being well washed in some boiling water, is dissolved in a solution of cyanide of potassium. If a clean electrotype is plunged into this solution, it is immediately covered with a very thin coating of silver, which of course would soon wear off, and in order to increase the thickness of the silver deposit, a single cell arrangement may be constructed of a large gallipot containing a wide porous cell and a circle of amalgamated zinc around it; the arrangement is set in action by pouring a solution of salt (or, still better, sal ammoniac) into and around the porous vessel, and the silvering solution into the latter; a connecting wire passes from the zinc, and the article being attached to it, is now plunged into the porous cell, when a current of electricity slowly passes and deposits the silver on the copper article. (Fig. 189.)

Fig. 189.

The gallipot containing the solution of sal ammoniac, with the circular amalgamated zinc with wire and binding screw to which the medal is attached, and contained in the porous vessel holding the silvering solution and medal.

Twelfth Experiment.

Separate batteries and large troughs containing a solution of cyanide of silver in cyanide of potassium are used on a grand scale in the electro-plating establishment of Messrs. Elkington of Birmingham, where the finest specimens of the art are to be obtained; a plate of silver being attached to the anode to supply the loss of silver in these troughs.

Thirteenth Experiment.

The art of gilding by the agency of electricity is quite as simple as the processes already described, although greater care is necessary to avoid any loss of the precious metal. A small bit of gold is dissolved in a mixture of three parts muriatic acid and one of nitric acid, which forms the chloride of gold. This is then digested with an excess of calcined magnesia, and the gold is precipitated as an oxide of the metal; the latter is collected and washed, and then boiled in strong nitric acid to remove the magnesia clinging to it, and being again thoroughly washed with water, is dissolved in a solution of cyanide of potassium, forming a solution of cyanide of gold and potassium, which may be placed in the porous cell of the single cell arrangement already described in the Eleventh Experiment.