As the permanent gases head the list, they will first engage our attention, beginning with the element oxygen—Symbol O, combining proportion 8. There is nothing can give a better idea of the enormous quantity of oxygen present in the animal, vegetable, and mineral kingdoms, than the statement that it represents one-third of the weight of the whole crust of the globe. Silica, or flint, contains about half its weight of oxygen; lime contains forty per cent.; alumina about thirty-three per cent. In these substances the element oxygen remains inactive and powerless, chained by the strong fetters of chemical affinity to the silicium of the flint, the calcium of the lime, and the aluminum of the alumina. If these substances are heated by themselves they will not yield up the large quantity of oxygen they contain.
Nature, however, is prodigal in her creation, and hence we have but to pursue our search diligently to find a substance or mineral containing an abundance of oxygen, and part of which it will relinquish by what used to be called by the "old alchemists" the torture of heat. Such a mineral is the black oxide of manganese, or more correctly the binoxide of manganese, which consists of one combining proportion of the metal manganese—viz., 27.6, and two of oxygen—viz., 8 × 2 = 16. If three proportions of the binoxide of manganese are heated to redness in an iron retort, they yield one proportion (equal to 8) of oxygen, and all that has just been explained by so many words is comprehended in the symbols and figures below:—
3 MnO2 = Mn3O4 + O.
Thus the 3 MnO2 represent the three proportions of the binoxide of manganese before heat is applied, whilst the sign =, the sign of equation (equal to), is intended to show that the elements or compounds placed before it produce those which follow it; hence the sequel Mn3O4 + O shows that another compound of the metal and oxygen is produced, whilst the + O indicates the liberated oxygen gas. The iron retort employed to hold the mineral should be made of cast iron in preference to wrought iron, as the latter is very soon worn out by contact with oxygen at a red heat. A gun-barrel will answer the purpose for an experiment on the small scale, to which must be adapted a cock and piece of pewter tubing. Such a make-shift arrangement may do very well when nothing better offers; but as a question of expense, it is probably cheaper in the end to order of Messrs. Simpson and Maule, or of Messrs. Griffin, or of Messrs. Bolton, a cast-iron bottle, or cast-iron retort, as it is termed, of a size sufficient to prepare two gallons of oxygen from the binoxide of manganese, which, with four feet of iron conducting-pipe, and connected to the bottle with a screw, does not cost more than six shillings—an enormous dip, perhaps, in the juvenile pocket, and therefore we shall indicate presently a still cheaper apparatus for the same purpose. (Fig. 93.)
Fig. 93.
a. The iron bottle, containing the black oxide of manganese, with pipe passing to the pneumatic trough, b b, in which is fixed a shelf, c, perforated with a hole, under which the end of the pipe is adjusted, and the gas passes into the gas-jar, d.
The oxygen is conveyed to a square tin box provided with a shelf at one end, perforated with several holes at least one inch in diameter, called the pneumatic trough; any wooden trough, butter or wash-tub, foot-pan or bath, provided with a shelf, may be raised by the same title to the dignity of a piece of chemical apparatus. The gas jar must be filled with water by withdrawing the stopper and pressing it down into the trough, and when the neck is below the level of the water, the stopper is again inserted, and the jar with the water therein contained lifted steadily on to the shelf, the entry of atmospheric air being prevented by keeping the lower part of the gas jar, called the welt, under the water. Sometimes the pneumatic trough contains so small a quantity of water that on raising the gas jar to the shelf the liquid does not cover the bottom, and the air rushes up in large bubbles. Under these circumstances it is better to provide a gallon stone jug full of water, so that when the jar is being raised to the shelf it may be thrust into the trough (on the same principle as the crow and the pitcher in the fable), and thus by its bulk (as the stones in the pitcher) raise the water to the proper level. When the gas jar is about half filled with gas the jug may be withdrawn. This arrangement saves the trouble of constantly adding and baling out water from the pneumatic trough. (Fig. 94.)
Fig. 94.