Place some sulphur in a little copper ladle attached to a wire, and called a deflagrating spoon, passed through a round piece of zinc or brass plate and cork, so that the latter acts as an adjusting arrangement to fix the wire at any point required. The combustion of the sulphur, previously feeble, now assumes a remarkable intensity, and a peculiar coloured light is generated, whilst the sulphur unites with the oxygen, and forms sulphurous acid gas. It produces, in fact, the same gas which is formed by burning an ordinary sulphur match. This compound is valuable as a disinfectant, and is a very important bleaching agent, being most extensively employed in the whitening of straw employed in the manufacture of straw bonnets. It is an acid gas, as Lavoisier found, and this property may be detected by pouring a little tincture of litmus into the bottom of the plate in which the gas jar stands. The blue colour of the litmus is rapidly changed to red, and it might be thought that no further argument could possibly be required to prove that oxygen was the acidifying agent, the more particularly as the result is the same in the next illustration.
Third Experiment.
Cut a small piece from an ordinary stick of phosphorus under water, take care to dry it properly with a cloth, and after placing it in a deflagrating spoon, remove the stopper from the gas-jar, as there is no fear of the oxygen rushing away, because it is somewhat heavier than atmospheric air; and then, after placing the spoon with the phosphorus in the neck of the jar, apply a heated wire and pass the spoon at once into the middle of the oxygen; in a few seconds a most brilliant light is obtained, and the jar is filled with a white smoke; as this subsides, being phosphoric acid, and perfectly soluble in water, the same litmus test may be applied, when it is in like manner changed to red. The acid obtained is one of the most important constituents of bone.
Fourth Experiment.
A bit of bark-charcoal bound round with wire is set on fire either by holding it in the flame of a spirit-lamp, or by attaching a small piece of waxed cotton to the lower part, and igniting this; the charcoal may then be inserted into a bottle of oxygen, when the most brilliant scintillations occur. After the combustion has ceased and the whole is cool, a little tincture of litmus may also be poured in and shaken about, when it likewise turns red, proving for the third time the generation of an acid body, called carbonic acid—an acid, like the others already mentioned, of great value, and one which Nature employs on a stupendous scale as a means of providing plants, &c., with solid charcoal. Carbonic acid, a virulent poison to animal life, is, when properly diluted, and as contained in atmospheric air, one of the chief alimentary bodies required by growing and healthy plants.
In three experiments acid bodies have been obtained; can we speculate on the result of the next?
Fifth Experiment.
Into a deflagrating spoon place a bit of potassium, set this on fire by holding it in the spoon in the flame of a spirit-lamp, and then rapidly plunge the burning metal into a bottle of oxygen. A brilliant ignition occurs in the deflagrating spoon for a few seconds, and there is little or no smoke in the jar. The product this time is a solid, called potash, and if this be dissolved in water and filtered, it is found to be clear and bright, and now on the addition of a little tincture of litmus to one half of the solution, it is wholly unaffected, and remains blue; but if with the other half a small quantity of tincture of turmeric is mixed, it immediately changes from a bright yellow solution to a reddish-brown, because turmeric is one of the tests for an alkali; and thus is ascertained by the help of this and other tests that the result of the combustion is not an acid, but an alkali. The experiment is made still more satisfactory by burning another bit of potassium in oxygen and dissolving the product in water, and if any portion of the reddened liquid derived from the sulphurous, phosphoric, and carbonic acids taken from the previous experiments, be added to separate portions of the alkaline solution, they are all restored to their original blue colour, because an acid is neutralized by an alkali; and the experiment is made quite conclusive by the restoration of the reddened turmeric to a bright yellow on the addition of a solution of either of the three acids already named. Moreover, an acid need not contain a fraction of oxygen, as there is a numerous class of hydracids, in which the acidifying principle is hydrogen instead of oxygen, such as the hydrochloric, hydriodic, hydro-bromic, and hydrofluoric acids.