Hydrogen (υδωρ, water; γενναω, I give rise to), so termed by Lavoisier—called by other chemists inflammable air, and phlogiston. Symbol, H; combining properties, 1. The lightest known form of matter.
Every 100 parts by weight of water contain 11 parts of hydrogen gas; and as the quantity of water on the surface of the earth represents at least two-thirds of the whole area, the source of this gas, like that of oxygen or nitrogen, is inexhaustible. Van Helmont, Mayow, and Hales had shown that certain inflammable and peculiar gases could be obtained, but it was reserved for the rigidly philosophic mind of Cavendish to determine the nature of the elements contained in, and giving a speciality to, the inflammable gases of the older chemists. By acting with dilute acids upon iron, zinc, and tin, Cavendish liberated an inflammable elastic gas; and he discovered nearly all the properties we shall notice in the succeeding experiments, and especially demonstrated the composition of water in his paper read before the Royal Society in the year 1784.
First Experiment.
Hydrogen is prepared in a very simple manner, by placing some zinc cuttings in a bottle, to which is attached a cork and pewter or bent glass tube, and pouring upon the metal some dilute sulphuric or hydrochloric acid. Effervescence and ebullition take place, and the gas escapes in large quantities, water being decomposed; the oxygen passes to the zinc, and forms oxide of zinc, and this uniting with the sulphuric acid forms sulphate of zinc, which may be obtained after the escape of the hydrogen by evaporation and crystallization. (Fig. 110.)
Zn + HO.SO3 = ZnO.SO3 + H;
or,
Zn + HCl = ZnCl + H.
In nearly all the processes employed for the generation of hydrogen gas, a metal is usually employed, and this fact has suggested the notion that hydrogen may possibly be a metal, although it is the lightest known form of matter; and it will be observed in all the succeeding experiments that a metallic substance will be employed to take away the oxygen and displace the hydrogen.
Fig. 110.
a. Bottle containing zinc cuttings and water and fitted with a cap and two tubes, the one marked b, containing a funnel, conveys the sulphuric acid to the zinc and water, whilst the gas escapes through the pipe c.