When the stuffs have acquired the desired shade, they are first to be washed in common water, and then in a very weak solution of hydrochloric acid (about one part in a thousand); after this they are again rinsed in pure water.
The Indian vat is much more easily managed than the foregoing; it presents less danger of failure, from the fact that it is quickly exhausted, and also from the fermentative process, which is so difficult to govern in the pastel vat; this vat not having time to change in character. It is prepared by first introducing an equal quantity of madder and of bran, and a triple quantity of potash; this is to be gradually heated until it reaches a temperature of 167° Fah., and we then add to it the indigo, thoroughly agitating the matters for half an hour. The vat is maintained at a temperature of 86° to 100° Fah., by keeping it closely covered, and at the same time the mixture is to be stirred occasionally at intervals of twelve hours. It should by this time present a beautiful green shade, the liquor being surmounted by a copper-colored pellicle and a purplish froth. We may now commence the dyeing, following the same course as with the pastel vat; but the stirrings being here repeated much more frequently than with the other mixture, we can dye a larger quantity of wool within a given time. When the vat ceases to give a brilliant blue, we must altogether renew it; if it be merely weakened, we add to it a small quantity of freshly prepared liquor containing a few pounds of potash, and a little less bran and madder. In giving the dark and the clear sky blues, we must be careful to employ a quantity of indigo proportioned to the color which we wish to obtain, or, better still, we may use the previously exhausted vat for the dark blue.
When exposed to the influence of the putrid fermentation, indigo is decomposed and loses its color. If rendered soluble, it obeys the impulse communicated to the azotized matters with which it is brought into contact, although, if macerated in pure water at the ordinary temperature, it is itself decomposed with great difficulty.
The pastel and the woad are very prone to the putrid fermentation, by reason of the large quantity of azotized matters which they contain, as do all the cruciferæ; they require therefore considerable care in their employment.
When a vat is mounted, if the fermentation be allowed to continue unchecked, after the appearance of the blue froth and the other signs already indicated, the liquor will acquire a yellow color similar to that of beer; the froth will become white; it will give out a stale smell and lose its ammoniacal odor; after a few days it will turn whitish, and exhale a smell at first similar to that of putrefied animal substances; then it will acquire the odor of rotten eggs, and set free sulphuretted hydrogen. The lime in the pastel and the woad vats, and the tartar-lee and potash in the other mixtures, are used for the purpose of preventing these accidents.
Besides the oxygenated compound, which is formed by the combination of oxygen with the extractive matters of the plants held in digestion, there is a production of carbonic acid which saturates the alkaline lee, and forms a carbonate of lime in the pastel vat. We find this attached to the sides of the vat in such quantity that the inside of these vessels becomes incrusted with it to a considerable depth. It is this product which dyers call the tartar of the vat; it effervesces with acids, and gives on analysis carbonic acid, lime, and a few particles of indigo. In the potash vat the solubility of the carbonate of potash prevents its deposition; but it is very probable that we have even here a formation of some carbonated products, perhaps in part formed at the expense of the carbonic acid of the air.
The soluble extractive principle being the only matter which remains in solution in the bath with the indigo, the lime, &c., we have formed deposits which, varying both in their volume and in the greater or less facility with which they are precipitated during the various periods of fermentation, lead to a more or less considerable waste of time. If we plunge a piece of woollen tissue into a vat which has been recently stirred, it will acquire a dark color, and will be found covered with brown stains which are with difficulty removed. When the woad or paste vat has been stirred, it need be left two or three hours only before plunging in the stuff, at least during the early months of its working, inasmuch as the pastel, being but slightly divided and attenuated, is readily precipitated; but when, by reason of its extreme division, in consequence of repeated operations, it is thrown down with less facility, the dipping should not be performed oftener than three times in the day.
The Indian vat requires less time than the others; we may even dye with it an hour after stirring the mixture. The potash, being soluble, forms no precipitate; while the ligneous fibre of the madder and the pellicles of the bran become deposited with great facility. We can also dip with these vats much oftener than with those made by pastel or woad.