The Chemistry, Properties and Tests of Precious Stones

by John Mastin

The character of the matrix is also in a great measure the cause of the variety of the stone, for it is obvious that the same salt-charged aqueous solution which undergoes change in and on ironstone would result in an entirely different product from that resting on or embedded in silica.

Following out the explanation of the aqueous solution, in which the earth-crust constituents are secreted, we find that the rarer and more precious metals do not generally enter into the composition of precious stones—which fact may advisedly be repeated. It is, of course, to be expected that beryllium will be found in the emerald, since it is under the species beryl, and zirconium in zircon; but such instances are the exception, and we may well wonder at the actions of the infinite powers of nature, when we reflect that the rarest, costliest and most beautiful of all precious stones are the simplest in their constituents.

Thus we find the diamond standing unique amongst all gems in being composed of one element only—carbon—being pure crystallised carbon; a different form from graphite, it is true, but, nevertheless, pure carbon and nothing else. Therefore, from its chemical, as well as from its commercial aspect, the diamond stands alone as the most important of gems.

The next in simplicity, whilst being the most costly of all, is the ruby, and with this may be classed the blue sapphire, seeing that their chemical constituents are exactly the same, the difference being one of colour only. These have two elements, oxygen and aluminium, which important constituents appear also in other stones, but this example is sufficient to prove their simplicity of origin.

Another unique stone is the turquoise, in that it is the only rare gem essentially containing a great proportion of water, which renders it easily liable to destruction, as we shall see later. It is a combination of alumina, water, and phosphoric acid, and is also unique in being the only known valuable stone containing a phosphate.

Turning to the silica series, we again find a number of gems with two elements only, silica—an important constituent of the earth's crust—and oxygen—an important constituent of atmospheric air. In this group may be mentioned the opal, amethyst, agate, rock-crystal, and the like, as the best known examples, whilst oxygen appears also mostly in the form of oxides, in chrysoberyl, spinel, and the like. This silica group is extremely interesting, for in it, with the exception of the tourmaline and a few others, the composition of the gems is very simple, and we find in this group such stones as the chrysolite, several varieties of topaz, the garnet, emerald, etc., etc.

Malachite and similar stones are more ornamental than precious, though they come in the category of precious stones. These are the carbonate series, containing much carbonic acid, and, as may be expected, a considerable proportion of water in their composition, which water can, of course, be dispelled by the application of heat, but to the destruction of the stone.

From all this will be seen how strong is the theory of aqueous percolation, for, given time and pressure, water charged with earth-crust constituents appears to be the origin of the formation of all precious stones; and all the precious stones known have, when analysed, been found to be almost exclusively composed of upper-earth-crust constituents; the other compounds which certain stones contain may, in all cases, be traced to their matrix, or to their geological or mineralogical situation.

In contradistinction to this, the essentially underground liquids, with time and pressure, form metallic minerals and mineralise the rocks, instead of forming gems.

Thus we see that in a different class of minerals—compounds of metals with the sulphates, such as sulphuric acid and compounds; also those containing the metallic sulphides; in cases where the metalliferous ores or the metallic elements enter into composition with the halogens—bromine, chlorine, fluorine, and iodine—in all these, precious stones are comparatively common, but the stones of these groups are invariably those used for decorative or ornamental purposes, and true "gems" are entirely absent.