Sometimes the zinc ions which have got into solution meet with sulphate ions and form zinc sulphate molecules. But if they do these molecules split up sooner or later into ions again. In the upper part of the liquid in the jar, therefore, there are sulphate 25ions which are negative and two kinds of positive ions, namely, the hydrogen ions and the zinc ions.
Before the zinc ions began to crowd in there were just enough hydrogen ions to go with the sulphate ions. As it is, the entrance of the zinc ions has increased the number of positive ions and now there are too many. Some of the positive ions, therefore, and particularly the hydrogen ions, because the sulphate prefers to associate with the zinc ions, can’t find enough playfellows and so go down in the jar.
Down in the bottom of the jar the hydrogen ions find more sulphate ions to play with, but that leaves the copper ions which used to play with these sulphate ions without any playmates. So the copper ions go still further down and join with the copper atoms of the copper plate. They haven’t much right to do so, for you remember that they haven’t their proper number of electrons. Each copper ion lacks two electrons of being a copper atom. Nevertheless they join the copper plate. The result is a plate of copper which has too few electrons. It needs two electrons for every copper ion which joins it.
How about the zinc plate? You remember that it has two electrons more than it needs for every zinc ion which has left it. If only the extra electrons on the negative zinc plate could get around to the positive copper plate. They can if we connect a wire from one plate to the other. Then the electrons from the zinc stream into the spaces between the atoms of the wire and push ahead of them the electrons 26which are wandering around in these spaces. At the other end an equal number of electrons leave the wire to satisfy the positive copper plate. So we have a stream of electrons in the wire, that is, a current of electricity and our battery is working.
That’s the sort of a battery I used to play with. If you understand it you can get the general idea of all batteries. Let me express it in general terms.
At the negative plate of a battery ions go into solution and electrons are left behind. At the other end of the battery positive ions are crowded out of solution and join the plate where they cause a scarcity of electrons; that is, make the plate positive. If a wire is connected between the two plates, electrons will stream through it from the negative plate to the positive; and this stream is a current of electricity.
Pl. III.–Dry Battery for Use in Audion Circuits (Courtesy of National Carbon Co., Inc.)
Storage Battery (Courtesy of the Electric Storage Battery Co.).