Letters of a Radio-Engineer to His Son

by John Mills

When I was a boy we used to make our own batteries for our experiments. That was before storage batteries became as widely used as they are to-day when everybody has one in the starting system of his automobile. That was also before the day of the small dry battery such as we use in pocket flash lights. The batteries which we made were like those which they used on telegraph systems, and were sometimes called “gravity” batteries. Of course, we tried several kinds and I believe I got quite a little acid around the house at one time or another. I’ll tell you about only one kind but I shall use the words “electron,” “proton,” “nucleus,” “atom,” and “molecule,” about some of which nothing was known when I was a boy.

We used a straight-sided glass jar which would hold about a gallon. On the bottom we set a star shaped arrangement made of sheets of copper with a long wire soldered to it so as to reach up out of the jar. Then we poured in a solution of copper sulphate until the jar was about half full. This solution was made by dissolving in water crystals of “blue vitriol” which we bought at the drug store.

17Blue vitriol, or copper sulphate as the chemists would call it, is a substance which forms glassy blue crystals. Its molecules are formed of copper atoms, sulphur atoms, and oxygen atoms. In each molecule of it there is one atom of copper, one of sulphur and four of oxygen.

When it dissolves in water the molecules of the blue vitriol go wandering out into the spaces between the water molecules. But that isn’t all that happens or the most important thing for one who is interested in making a battery.

Each molecule is formed by six atoms, that is by six little groups of electrons playing about six little nuclei. About each nucleus there is going on a game but some of the electrons are playing in the game about their own nucleus and at the same time taking some part in the game which is going on around one of the other nuclei. That’s why the groups or atoms stay together as a molecule. When the molecules wander out into the spaces between the water molecules something happens to this complicated game.

It will be easiest to see what sort of thing happens if we talk about a molecule of ordinary table salt, for that has only two atoms in it. One atom is sodium and one is chlorine. The sodium molecule has eleven electrons playing around its nucleus. Fairly close to the nucleus there are two electrons. Then farther away there are eight more and these are having a perfect game. Then still farther away from the nucleus there is a single lonely electron.

The atom of chlorine has seventeen electrons which 18play about its nucleus. Close to the nucleus there are two. A little farther away there are eight just as there are in the sodium atom. Then still farther away there are seven.

I am going to draw a picture (Fig. 1) to show what I mean, but you must remember that these electrons are not all in the same plane as if they lay on a sheet of paper, but are scattered all around just as they would be if they were specks on a ball.

You see that the sodium atom has one lonely electron which hasn’t any play fellows and that the chlorine atom has seven in its outside circle. It appears that eight would make a much better game. Suppose that extra electron in the sodium atom goes over and plays with those in the chlorine atom so as to make eight in the outside group as I have shown Fig. 2. That will be all right as long as it doesn’t get out of sight of its own nucleus because you remember that the sodium nucleus is responsible for eleven electrons. The lonely electron of the sodium atom needn’t be lonely any more if it can persuade its nucleus to stay so close to the chlorine atom that it can play in the outer circle of the chlorine atom.