If silver has been applied to the nerves, and zinc to the muscles, the irritability of the latter increases in proportion to the time they have remained in the chain. By this method, the thighs of frogs have been revivified in some degree, and afterwards became sensible to stimuli that before had ceased to act on them. By distributing the metals in an inverse manner, applying zinc to the nerves, and silver to the muscles, an effect absolutely contrary is observed; and the muscles that possessed the most lively irritability when placed in the chain, seem to be rendered entirely paralytic if they remain long in this situation.
This difference evidently depends on the direction of the galvanic fluid, determined towards the muscles or nerves, according to the manner in which these metals are disposed; and this is of some importance to be known for the application of galvanic means to the cure of diseases.
M. Volta’s apparatus is as follows:—Raise a pile, by placing a plate of zinc, a flat piece of wet card, and a plate of silver, successively; then a second piece of zinc, &c. until the elevation is several feet high; for the effects are greater in proportion to its height; then touch both extremities of the pile, at the same instant, with one piece of iron wire: at the moment of contact, a spark is excited from the extremities of the pile, and luminous points are often perceived at different heights, where the zinc and silver come into mutual contact. The zinc end of this pile appears to be negatively electrified; that formed by the silver, on the contrary, indicates marks of positive electricity.
If we touch both extremities of the pile, after having dipped our hands into water, or, what is better, a saline solution, a commotion, followed by a disagreeable pricking in the fingers and elbow, is felt.
If we place, in a tube filled with water, and hermetically closed by two corks, the extremities of two wires of the same metal, which are in contact at the other extremity, one with the summit, the other with the base of the pile; these ends, even when separated only by the space of a few lines, experience evident changes at the instant the extremities of the pile are touched: the wire in contact with that part of the pile composed of zinc, becomes covered with bullæ of hydrogen gas; that which touches the extremity formed by silver, becomes oxydated. Fourcroy attributes this phenomenon to the decomposition of water by the galvanic fluid, which abandons the oxygen to the iron that touches the positive extremity of the pile; then conducts the other gas invisibly to the end of the other wire, there to be disengaged.
From the numerous experiments of Mr. Davy, many new and important facts have been established, and Galvanism has been found to be one of the most powerful agents in chemistry. By its influence, platina wire has been melted; gold, silver, copper, and most of the metals, have easily been burnt! the fixed alkalis, and many of the earths, have been made to appear as consisting of a metallic base and oxygen; compound substances, which were before extremely difficult to decompose, are now, by the aid of Galvanism, easily resolved into their constituent.
CHAP. LXXI.
CURIOSITIES RESPECTING MAGNETISM.